Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| p-Hydroxybenzenesulfonic acid-formaldehyde solid acid resin for the conversion of fructose and glucose to 5-hydroxymethylfurfural | |
Li, Wenzhi1; Zhang, Tingwei1; Xin, Haosheng2; Su, Mingxue3; Ma, Longlong4 ; Jameel, Hason5; Chang, Hou-min5; Pei, Gang1
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| 2017 | |
| Source Publication | RSC ADVANCES
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| Volume | 7Issue:44Pages:27682-27688 |
| Abstract | A novel solid p-hydroxybenzenesulfonic acid-formaldehyde resin (SPFR) was prepared via a straightforward hydrothermal method. The catalytic properties of SPFR solid acids were evaluated in the dehydration reaction of fructose and glucose to 5-hydroxymethylfurfural (HMF). SEM, TEM, N-2 adsorption-desorption, elemental analysis (EA), thermogravimetric analysis (TGA), and FT-IR were used to explore the effects of catalyst structure and composition on the HMF preparation from fructose. The effects of reaction time and temperature on the dehydration of fructose and glucose were also investigated. An HMF yield as high as 82.6% was achieved from fructose at 140 degrees C after 30 min, and 33.0% was achieved from glucose at 190 degrees C in 30 min. Furthermore, the recyclability of SPFR for the HMF production from fructose in 5 cycles was good. |
| Subtype | Article |
| WOS Headings | Science & Technology ; Physical Sciences |
| DOI | 10.1039/c7ra03155f |
| WOS Subject Extended | Chemistry |
| WOS Keyword | GAMMA-VALEROLACTONE ; IONIC LIQUID ; CATALYTIC CONVERSION ; BIPHASIC SYSTEM ; LEVULINIC ACID ; MCM-41 SILICA ; LEWIS-ACID ; DEHYDRATION ; BIOMASS ; CHITOSAN |
| Indexed By | SCI |
| Language | 英语 |
| Funding Organization | State Key Program of the National Natural Science Foundation of China(51536009) ; National Key Technology R&D Program of China(2015BAD15B06) ; Science and Technological Fund of the Anhui Province(1508085J01) |
| WOS Subject | Chemistry, Multidisciplinary |
| WOS ID | WOS:000402166600059 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/14133 |
| Collection | 中国科学院广州能源研究所 |
| Affiliation | 1.Univ Sci & Technol China, Dept Thermal Sci & Energy Engn, Hefei 230026, Peoples R China 2.Anhui Jianzhu Univ, Inst Mat & Chem Engn, Hefei 230022, Peoples R China 3.Univ Sci & Technol China, Dept Chem, Hefei 230026, Peoples R China 4.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 5.North Carolina State Univ, Dept Forest Biomat, Raleigh, NC 27695 USA |
| Recommended Citation GB/T 7714 | Li, Wenzhi,Zhang, Tingwei,Xin, Haosheng,et al. p-Hydroxybenzenesulfonic acid-formaldehyde solid acid resin for the conversion of fructose and glucose to 5-hydroxymethylfurfural[J]. RSC ADVANCES,2017,7(44):27682-27688. |
| APA | Li, Wenzhi.,Zhang, Tingwei.,Xin, Haosheng.,Su, Mingxue.,Ma, Longlong.,...&Pei, Gang.(2017).p-Hydroxybenzenesulfonic acid-formaldehyde solid acid resin for the conversion of fructose and glucose to 5-hydroxymethylfurfural.RSC ADVANCES,7(44),27682-27688. |
| MLA | Li, Wenzhi,et al."p-Hydroxybenzenesulfonic acid-formaldehyde solid acid resin for the conversion of fructose and glucose to 5-hydroxymethylfurfural".RSC ADVANCES 7.44(2017):27682-27688. |
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