p-Hydroxybenzenesulfonic acid-formaldehyde solid acid resin for the conversion of fructose and glucose to 5-hydroxymethylfurfural

doi:10.1039/c7ra03155f

GIEC OpenIR > 中国科学院广州能源研究所

	p-Hydroxybenzenesulfonic acid-formaldehyde solid acid resin for the conversion of fructose and glucose to 5-hydroxymethylfurfural
	Li, Wenzhi 1; Zhang, Tingwei 1; Xin, Haosheng 2; Su, Mingxue 3; Ma, Longlong4 ; Jameel, Hason 5; Chang, Hou-min 5; Pei, Gang 1
	2017
发表期刊	RSC ADVANCES
卷号	7 期号:44 页码:27682-27688
摘要	A novel solid p-hydroxybenzenesulfonic acid-formaldehyde resin (SPFR) was prepared via a straightforward hydrothermal method. The catalytic properties of SPFR solid acids were evaluated in the dehydration reaction of fructose and glucose to 5-hydroxymethylfurfural (HMF). SEM, TEM, N-2 adsorption-desorption, elemental analysis (EA), thermogravimetric analysis (TGA), and FT-IR were used to explore the effects of catalyst structure and composition on the HMF preparation from fructose. The effects of reaction time and temperature on the dehydration of fructose and glucose were also investigated. An HMF yield as high as 82.6% was achieved from fructose at 140 degrees C after 30 min, and 33.0% was achieved from glucose at 190 degrees C in 30 min. Furthermore, the recyclability of SPFR for the HMF production from fructose in 5 cycles was good.
文章类型	Article
WOS标题词	Science & Technology ; Physical Sciences
DOI	10.1039/c7ra03155f
研究领域[WOS]	Chemistry
关键词[WOS]	GAMMA-VALEROLACTONE ; IONIC LIQUID ; CATALYTIC CONVERSION ; BIPHASIC SYSTEM ; LEVULINIC ACID ; MCM-41 SILICA ; LEWIS-ACID ; DEHYDRATION ; BIOMASS ; CHITOSAN
收录类别	SCI
语种	英语
项目资助者	State Key Program of the National Natural Science Foundation of China(51536009) ; National Key Technology R&D Program of China(2015BAD15B06) ; Science and Technological Fund of the Anhui Province(1508085J01)
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000402166600059
引用统计	被引频次：32[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/14133
专题	中国科学院广州能源研究所
作者单位	1.Univ Sci & Technol China, Dept Thermal Sci & Energy Engn, Hefei 230026, Peoples R China 2.Anhui Jianzhu Univ, Inst Mat & Chem Engn, Hefei 230022, Peoples R China 3.Univ Sci & Technol China, Dept Chem, Hefei 230026, Peoples R China 4.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 5.North Carolina State Univ, Dept Forest Biomat, Raleigh, NC 27695 USA
推荐引用方式 GB/T 7714	Li, Wenzhi,Zhang, Tingwei,Xin, Haosheng,et al. p-Hydroxybenzenesulfonic acid-formaldehyde solid acid resin for the conversion of fructose and glucose to 5-hydroxymethylfurfural[J]. RSC ADVANCES,2017,7(44):27682-27688.
APA	Li, Wenzhi.,Zhang, Tingwei.,Xin, Haosheng.,Su, Mingxue.,Ma, Longlong.,...&Pei, Gang.(2017).p-Hydroxybenzenesulfonic acid-formaldehyde solid acid resin for the conversion of fructose and glucose to 5-hydroxymethylfurfural.RSC ADVANCES,7(44),27682-27688.
MLA	Li, Wenzhi,et al."p-Hydroxybenzenesulfonic acid-formaldehyde solid acid resin for the conversion of fructose and glucose to 5-hydroxymethylfurfural".RSC ADVANCES 7.44(2017):27682-27688.