Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| In-situ hydrogenation of model compounds and raw bio-oil over Ni/CMK-3 catalyst | |
Xu, Ying1,2,3 ; Li, Yanbin1; Wang, Congwei1,2,3; Wang, Chenguang1,2,3; Ma, Longlong1,2,3; Wang, Tiejun1,2,3; Zhang, Xinghua1,2,3; Zhang, Qi1,2,3
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| 2017-06-15 | |
| Source Publication | FUEL PROCESSING TECHNOLOGY
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| Volume | 161Pages:226-231 |
| Abstract | Ni/CMK-3 catalyst, the mesoporous carbon material loading Ni activity, was prepared and used in the in-situ hydrogenation of mixed model compounds (including acetone, acetic acid, furfural, o-cresol, ethanediol and water) of bio-oil (MCB) and actual bio-oil in this paper. The effects of hydrogen donors, solvents and the dosages of catalyst were all investigated in the in-situ hydrogenation process. The results showed that the hydrogen donor of methanol, ethanol and formic acid could all provide hydrogen for the in-situ hydrogenation but the product distributions of bio-oils were different after in-situ hydrogenation. Using alcohols as hydrogen donors, esterification reaction happened between the hydrogen donors and acetic acid. The formic acid could promote the phenols conversion but the conversion of acetic acid was restrained. When the radio of water and methanol was 10:3 and 10:5, most of ketones and aldehydes in the raw bio-oil converted to alcohols and the conversion of acids and phenols was beyond 50%. The contents of alcohols and esters in raw bio-oil increased from 18.52% to 51.14% and 48.21%. (C) 2016 Elsevier B.V. All rights reserved. |
| Subtype | Article |
| Keyword | Bio-oil In-situ Hydrogenation Model Compounds Ni-base Catalyst Cmk-3 |
| WOS Headings | Science & Technology ; Physical Sciences ; Technology |
| DOI | 10.1016/j.fuproc.2016.08.018 |
| WOS Subject Extended | Chemistry ; Energy & Fuels ; Engineering |
| WOS Keyword | FAST PYROLYSIS ; PHENOLIC-COMPOUNDS ; NI CATALYST ; HYDRODEOXYGENATION ; ESTERIFICATION ; CONVERSION ; CARBON ; HYDROCARBONS ; ALCOHOLS ; QUALITY |
| Indexed By | SCI |
| Language | 英语 |
| Funding Organization | Natural Science Foundation of China(51476178) ; Science and Technology Plan Key Project in Guangdong Province of China(2014A010106019) ; Youth Innovation Promotion Association CAS |
| WOS Subject | Chemistry, Applied ; Energy & Fuels ; Engineering, Chemical |
| WOS ID | WOS:000401047600027 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/14130 |
| Collection | 中国科学院广州能源研究所 |
| Affiliation | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 2.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 3.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Guangdong, Peoples R China |
| First Author Affilication | GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences |
| Recommended Citation GB/T 7714 | Xu, Ying,Li, Yanbin,Wang, Congwei,et al. In-situ hydrogenation of model compounds and raw bio-oil over Ni/CMK-3 catalyst[J]. FUEL PROCESSING TECHNOLOGY,2017,161:226-231. |
| APA | Xu, Ying.,Li, Yanbin.,Wang, Congwei.,Wang, Chenguang.,Ma, Longlong.,...&Zhang, Qi.(2017).In-situ hydrogenation of model compounds and raw bio-oil over Ni/CMK-3 catalyst.FUEL PROCESSING TECHNOLOGY,161,226-231. |
| MLA | Xu, Ying,et al."In-situ hydrogenation of model compounds and raw bio-oil over Ni/CMK-3 catalyst".FUEL PROCESSING TECHNOLOGY 161(2017):226-231. |
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