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Conversion of Cellulose to 5-Hydroxymethylfurfural using Inorganic Acidic Catalysts in the Presence of Pressurized Water Steam
Cai, Chiliu1,2,3,4; Liu, Qiying1,2,3; Tan, Jin1,2,3; Wang, Tiejun1,2,3; Zhang, Qi1,2,3; Ma, Longlong1,2,3
2017
Source PublicationBIORESOURCES
Volume12Issue:1Pages:1201-1215
AbstractTraditionally, 5-hydroxymethylfurfural ( HMF) is produced by using a water-organic solvent medium, which inevitably increases production costs and adds subsequent separation processes. To minimize cost and/or toxic organic solvent usage, this study presents an effective pathway for producing HMF from cellulose. The process uses a fixed bed reactor with a steam stripping process in which the cellulose is converted into HMF and other products in the presence of acidic inorganic salts. In the process, the cellulose was hydrolyzed to glucose, which was followed by isomerization to fructose and fructose dehydration into HMF. The produced HMF was easily vaporized into the gas phase, which avoided its conversion into undesired byproducts. An acceptable HMF yield of 28.2 mol% was obtained using KH2PO4 as the catalyst at 270 degrees C. This technology could be used to obtain both HMF and furfural ( FF) from different lignocellulosic biomasses. This stripping technology has advantages such as the lack of organic solvents, showing an alternative and green HMF and/or FF production from lignocellulosic biomass.
SubtypeArticle
KeywordCellulose Hmf Conversion Steam Stripping Process Fixed Bed
WOS HeadingsScience & Technology ; Technology
DOI10.15376/biores.12.1.1201-1215
WOS Subject ExtendedMaterials Science
WOS KeywordLIQUID-WATER ; LEVULINIC ACID ; BIOMASS ; HYDROCARBONS ; HYDROLYSIS ; PRETREATMENT ; DEHYDRATION ; MECHANISM ; SOLVENTS ; ZEOLITE
Indexed BySCI
Language英语
Funding OrganizationNational Science Foundation of China(51536009 ; 51576199 ; 51376185)
WOS SubjectMaterials Science, Paper & Wood
WOS IDWOS:000397065200088
Citation statistics
Cited Times:3[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/14076
Collection中国科学院广州能源研究所
Affiliation1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China
2.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
3.Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Guangdong, Peoples R China
4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
First Author AffilicationGuangZhou Institute of Energy Conversion,Chinese Academy of Sciences
Recommended Citation
GB/T 7714
Cai, Chiliu,Liu, Qiying,Tan, Jin,et al. Conversion of Cellulose to 5-Hydroxymethylfurfural using Inorganic Acidic Catalysts in the Presence of Pressurized Water Steam[J]. BIORESOURCES,2017,12(1):1201-1215.
APA Cai, Chiliu,Liu, Qiying,Tan, Jin,Wang, Tiejun,Zhang, Qi,&Ma, Longlong.(2017).Conversion of Cellulose to 5-Hydroxymethylfurfural using Inorganic Acidic Catalysts in the Presence of Pressurized Water Steam.BIORESOURCES,12(1),1201-1215.
MLA Cai, Chiliu,et al."Conversion of Cellulose to 5-Hydroxymethylfurfural using Inorganic Acidic Catalysts in the Presence of Pressurized Water Steam".BIORESOURCES 12.1(2017):1201-1215.
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