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One-step hydroprocessing of fatty acids into renewable aromatic hydrocarbons over Ni/HZSM-5: insights into the major reaction pathways
Xing, Shiyou1,2,3,4; Lv, Pengmei1,2,4,5; Wang, Jiayan1,6; Fu, Junying1,2,4; Fan, Pei1,2,3,4; Yang, Lingmei1,2,4; Yang, Gaixiu1,2,4; Yuan, Zhenhong1,2,4,5; Chen, Yong1,2,4
2017
发表期刊PHYSICAL CHEMISTRY CHEMICAL PHYSICS
卷号19期号:4页码:2961-2973
摘要For high caloricity and stability in bio-aviation fuels, a certain content of aromatic hydrocarbons (AHCs, 8-25 wt%) is crucial. Fatty acids, obtained from waste or inedible oils, are a renewable and economic feedstock for AHC production. Considerable amounts of AHCs, up to 64.61 wt%, were produced through the one-step hydroprocessing of fatty acids over Ni/HZSM-5 catalysts. Hydrogenation, hydrocracking, and aromatization constituted the principal AHC formation processes. At a lower temperature, fatty acids were first hydrosaturated and then hydrodeoxygenated at metal sites to form long-chain hydrocarbons. Alternatively, the unsaturated fatty acids could be directly deoxygenated at acid sites without first being saturated. The long-chain hydrocarbons were cracked into gases such as ethane, propane, and C-6-C-8 olefins over the catalysts' Bronsted acid sites; these underwent Diels-Alder reactions on the catalysts' Lewis acid sites to form AHCs. C-6-C-8 olefins were determined as critical intermediates for AHC formation. As the Ni content in the catalyst increased, the Bronsted-acid site density was reduced due to coverage by the metal nanoparticles. Good performance was achieved with a loading of 10 wt% Ni, where the Ni nanoparticles exhibited a polyhedral morphology which exposed more active sites for aromatization.
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
资助者National Natural Science Foundation of China(21576260) ; Natural Science Foundation of Guangdong Province(2016A030308004 ; Special Funds of Applied Science and Technology Research of Guangdong Province(2015B020241002) ; 2015A030313720) ; National Natural Science Foundation of China(21576260) ; Natural Science Foundation of Guangdong Province(2016A030308004 ; Special Funds of Applied Science and Technology Research of Guangdong Province(2015B020241002) ; 2015A030313720)
DOI10.1039/c6cp06327f
研究领域[WOS]Chemistry ; Physics
关键词[WOS]BIOMASS-DERIVED DIMETHYLFURAN ; DIELS-ALDER CYCLOADDITION ; OLEIC-ACID ; CATALYTIC CRACKING ; JET FUEL ; P-XYLENE ; SELECTIVE HYDROGENATION ; QUANTITATIVE CONVERSION ; VEGETABLE-OILS ; RANGE ALKANES
收录类别SCI
语种英语
资助者National Natural Science Foundation of China(21576260) ; Natural Science Foundation of Guangdong Province(2016A030308004 ; Special Funds of Applied Science and Technology Research of Guangdong Province(2015B020241002) ; 2015A030313720) ; National Natural Science Foundation of China(21576260) ; Natural Science Foundation of Guangdong Province(2016A030308004 ; Special Funds of Applied Science and Technology Research of Guangdong Province(2015B020241002) ; 2015A030313720)
WOS类目Chemistry, Physical ; Physics, Atomic, Molecular & Chemical
WOS记录号WOS:000394940400035
引用统计
被引频次:2[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/14059
专题中国科学院广州能源研究所
作者单位1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China
2.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou 510640, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
4.Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Peoples R China
5.Collaborat Innovat Ctr Biomass Energy, Zhengzhou 450002, Herts, Peoples R China
6.Univ Sci Technol China, Nano Sci & Technol Inst, Suzhou 215123, Peoples R China
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Xing, Shiyou,Lv, Pengmei,Wang, Jiayan,et al. One-step hydroprocessing of fatty acids into renewable aromatic hydrocarbons over Ni/HZSM-5: insights into the major reaction pathways[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS,2017,19(4):2961-2973.
APA Xing, Shiyou.,Lv, Pengmei.,Wang, Jiayan.,Fu, Junying.,Fan, Pei.,...&Chen, Yong.(2017).One-step hydroprocessing of fatty acids into renewable aromatic hydrocarbons over Ni/HZSM-5: insights into the major reaction pathways.PHYSICAL CHEMISTRY CHEMICAL PHYSICS,19(4),2961-2973.
MLA Xing, Shiyou,et al."One-step hydroprocessing of fatty acids into renewable aromatic hydrocarbons over Ni/HZSM-5: insights into the major reaction pathways".PHYSICAL CHEMISTRY CHEMICAL PHYSICS 19.4(2017):2961-2973.
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