Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| Effect of Ru Particle Size on Hydrogenation/Decarbonylation of Propanoic Acid Over Supported Ru Catalysts in Aqueous Phase | |
| Chen, Lungang; Li, Yuping; Zhang, Xinghua; Zhang, Qi; Wang, Tiejun; Ma, Longlong | |
| 2017 | |
| Source Publication | CATALYSIS LETTERS
 |
| Volume | 147Issue:1Pages:29-38 |
| Abstract | The aqueous-phase hydrogenation of propanoic acid was performed over the Ru/ZrO2 and Ru/Al2O3 catalysts with different Ru loading. Combined with multiple characterization techniques, such as H-2-TPR, XRD, CO-FTIR, and DRIFTS of propanoic acid, the effect of Ru loading on the decarbonylation/hydrogenation of propanoic acid was investigated. Although hydrogenation/decarbonylation of carboxylic acids were strongly affected by the nature of supports, the increase of metal loading can cause the larger Ru particles and more bare Ru metal sites, which can facilitate the C-C bond cleavage reaction derived from the decarbonylation of propanoyl species over Ru metal sites. |
| Subtype | Article |
| Keyword | Ru Loading Carboxylic Acid Hydrogenation Decarbonylation C-c Cleavage |
| WOS Headings | Science & Technology ; Physical Sciences |
| DOI | 10.1007/s10562-016-1877-4 |
| WOS Subject Extended | Chemistry |
| WOS Keyword | ACETIC-ACID ; CO ADSORPTION ; LACTIC-ACID ; RUTHENIUM CATALYSTS ; SUCCINIC ACID ; HYDROGENATION ; BIOMASS ; HYDROGENOLYSIS ; REDUCTION ; CHEMICALS |
| Indexed By | SCI |
| Language | 英语 |
| Funding Organization | National Natural Science Foundation of China(51306189) ; Science and Technology Program of Guangdong Province(2014A010106022) ; Comprehensive Strategic Cooperation Project of Guangdong Province ; Chinese Academy of Sciences(2012B090400042) ; China-EU SMEs Cooperation Fund for Energy Conservation Research Project(SQ2013ZOB000002) |
| WOS Subject | Chemistry, Physical |
| WOS ID | WOS:000394139200004 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/14037 |
| Collection | 中国科学院广州能源研究所 |
| Affiliation | Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China |
| Recommended Citation GB/T 7714 | Chen, Lungang,Li, Yuping,Zhang, Xinghua,et al. Effect of Ru Particle Size on Hydrogenation/Decarbonylation of Propanoic Acid Over Supported Ru Catalysts in Aqueous Phase[J]. CATALYSIS LETTERS,2017,147(1):29-38. |
| APA | Chen, Lungang,Li, Yuping,Zhang, Xinghua,Zhang, Qi,Wang, Tiejun,&Ma, Longlong.(2017).Effect of Ru Particle Size on Hydrogenation/Decarbonylation of Propanoic Acid Over Supported Ru Catalysts in Aqueous Phase.CATALYSIS LETTERS,147(1),29-38. |
| MLA | Chen, Lungang,et al."Effect of Ru Particle Size on Hydrogenation/Decarbonylation of Propanoic Acid Over Supported Ru Catalysts in Aqueous Phase".CATALYSIS LETTERS 147.1(2017):29-38. |
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