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Direct synthesis and characterization of pore-broadened Al-SBA-15
Xing, Shiyou1,2,3,4; Lv, Pengmei1,2,4,5; Fu, Junying1,2,4; Wang, Jiayan1,6; Fan, Pei1,2,3,4; Yang, Lingmei1,2,4; Yuan, Zhenhong1,2,4,5
2017-02-01
发表期刊MICROPOROUS AND MESOPOROUS MATERIALS
卷号239页码:316-327
摘要A series of pore-broadened Al-SBA-15 samples were synthesized using a direct hydrothermal method. The effects of aluminum incorporation, assembling temperature, and co-solvent (1,3,5-trimethylbenzene (TMB)) content were investigated by low-angle XRD, N-2 adsorption and desorption isotherm analysis, SEM, TEM, NH3-TPD, FTIR, pyridine-IR, and Al-27 NMR. The results indicated that aluminum incorporation (Si/Al ratio = 10) increased the pore size of SBA-15 from 5.66 to 10.13 nm. A small pore size of 6.55 nm was observed at a low assembling temperature of 30 degrees C, attributing to the inadequate stretching of the molecular template. An increased pore size of 8.45 nm was obtained at an assembling temperature of 60 degrees C because of the partial hydrophobization of the hydrophilic groups, whereas a high temperature of 70 degrees C resulted in the generation of least ordered pores. The hydrophobic co-solvent TMB showed a significant broadening level as a result of its effective fusion into the hydrophobic micelle cores. A highly ordered pore framework with a pore size of 18 nm was obtained at a TMB/P-123 ratio of 0.25, which was found to be optimum. More or less TMB led to the generation of mesocellular silica-aluminum foams with a complete loss of regularity. The Al-27 NMR results showed that aluminum was mostly tetrahedrally coordinated. The NH3-TPD and pyridine-IR detection results indicated that a number of weak and medium acid sites (as Bronsted and Lewis acid sites) existed in Al-SBA-15 pore-broadened by TMB. (C) 2016 Elsevier Inc. All rights reserved.
文章类型Article
关键词Pore-broadening Al-sba-15 Direct Synthesis Characterization
WOS标题词Science & Technology ; Physical Sciences ; Technology
资助者National Natural Science Foundation of China(21576260) ; Natural Science Foundation of Guangdong Province(2016A030308004 ; Special Funds of Applied Science and Technology Research of Guangdong Province(2015B020241002) ; 2015A030313720) ; National Natural Science Foundation of China(21576260) ; Natural Science Foundation of Guangdong Province(2016A030308004 ; Special Funds of Applied Science and Technology Research of Guangdong Province(2015B020241002) ; 2015A030313720)
DOI10.1016/j.micromeso.2016.10.018
研究领域[WOS]Chemistry ; Science & Technology - Other Topics ; Materials Science
关键词[WOS]MESOPOROUS SILICA ; HYDROTHERMAL STABILITY ; PT/AL-SBA-15 CATALYSTS ; ACIDIC PROPERTIES ; PHASE-TRANSITION ; MOLECULAR-SIEVES ; SI/AL RATIO ; GAS OIL ; SBA-15 ; MCM-41
收录类别SCI
语种英语
资助者National Natural Science Foundation of China(21576260) ; Natural Science Foundation of Guangdong Province(2016A030308004 ; Special Funds of Applied Science and Technology Research of Guangdong Province(2015B020241002) ; 2015A030313720) ; National Natural Science Foundation of China(21576260) ; Natural Science Foundation of Guangdong Province(2016A030308004 ; Special Funds of Applied Science and Technology Research of Guangdong Province(2015B020241002) ; 2015A030313720)
WOS类目Chemistry, Applied ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS记录号WOS:000389284300036
引用统计
被引频次:8[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/13988
专题中国科学院广州能源研究所
作者单位1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China
2.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
4.Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Guangdong, Peoples R China
5.Collaborat Innovat Ctr Biomass Energy, Zhengzhou 450002, Henan Province, Peoples R China
6.Univ Sci & Technol China, Nano Sci & Technol Inst, Suzhou 215123, Peoples R China
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Xing, Shiyou,Lv, Pengmei,Fu, Junying,et al. Direct synthesis and characterization of pore-broadened Al-SBA-15[J]. MICROPOROUS AND MESOPOROUS MATERIALS,2017,239:316-327.
APA Xing, Shiyou.,Lv, Pengmei.,Fu, Junying.,Wang, Jiayan.,Fan, Pei.,...&Yuan, Zhenhong.(2017).Direct synthesis and characterization of pore-broadened Al-SBA-15.MICROPOROUS AND MESOPOROUS MATERIALS,239,316-327.
MLA Xing, Shiyou,et al."Direct synthesis and characterization of pore-broadened Al-SBA-15".MICROPOROUS AND MESOPOROUS MATERIALS 239(2017):316-327.
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