Estimation of fixed-bed column parameters and mathematical modeling of breakthrough behaviors for adsorption of levulinic acid from aqueous solution using SY-01 resin

doi:10.1016/j.seppur.2016.10.016

GIEC OpenIR > 中国科学院广州能源研究所

	Estimation of fixed-bed column parameters and mathematical modeling of breakthrough behaviors for adsorption of levulinic acid from aqueous solution using SY-01 resin
	Lin, Xiaoqing 1,2,3; Huang, Qianlin 2,4; Qi, Gaoxiang 2,4; Shi, Silan 2,4; Xiong, Lian1,2,3 ; Huang, Chao 1,2,3; Chen, Xuefang 1,2,3; Li, Hailong 1,2,3; Chen, Xinde1,2,3
	2017-03-01
发表期刊	SEPARATION AND PURIFICATION TECHNOLOGY
ISSN	1383-5866
卷号	174 页码:222-231
摘要	Levulinic acid (LA) adsorption on a rnicroporous hyper-cross-linked adsorption resin, SY-01, from aqueous solution was performed in a fixed-bed column. Batch equilibrium isotherm was analyzed using Langmuir and Freundlich isotherm models, and the Langmuir isotherm model was found to fit the adsorption isotherm data well. The effects of feed flow rate (Q(f) = 1.0-5.0 mL/min), initial LA concentration (c(f) = 1.0-10.0 g/L), fixed-bed column length (L-c = 5.65-16.96 cm) and fixed-bed column diameter (D-c= 1.6-5.5 cm) on the adsorption characteristics of LA were investigated systematically. The results show that an increase in fixed-bed column length, fixed-bed column diameter, initial LA concentration and a decrease in feed flow rate improve the adsorption performance. Furthermore, a general rate model (GRM) was developed for predicting adsorption breakthrough curves of LA. The mathematical model results were in good agreement with the experimental data under various operating conditions, which confirmed that the GRM can successfully simulate this process. In addition, the values of Biot number (Bi) at different operating conditions were all more than 10, demonstrating intraparticle diffusion is the rate controlling step for the adsorption of LA on the resin. In conclusion, our results provide an important basis for future scale-up of the product recovery of LA from biomass hydrolysate. (C) 2016 Elsevier B.V. All rights reserved.
文章类型	Article
关键词	Levulinic Acid Fixed-bed Column Adsorption Breakthrough Curve Mathematical Model Resin Adsorbent
WOS标题词	Science & Technology ; Technology
DOI	10.1016/j.seppur.2016.10.016
研究领域[WOS]	Engineering
关键词[WOS]	PORE DIFFUSION-MODEL ; FERMENTATION BROTH ; POLYMERIC ADSORBENT ; MACROPOROUS RESIN ; ACTIVATED CARBON ; METHYLENE-BLUE ; PACKED-BEDS ; REMOVAL ; BUTANOL ; SEPARATION
收录类别	SCI
语种	英语
项目资助者	Science and Technology Planning Project of Guangdong Province, China(2016A010104009 ; Project of National Natural Science Foundation of China(51508547 ; Youth Innovation Promotion Association, Chinese Academy of Sciences(2015290) ; Project of Natural Science Foundation of Guangdong Province(2016A030310124) ; Foundation of Director of Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences(y407r41001) ; 2016A010105016) ; 21606229 ; 31600475)
WOS类目	Engineering, Chemical
WOS记录号	WOS:000389091700027
出版者	ELSEVIER SCIENCE BV
引用统计	被引频次：88[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/13983
专题	中国科学院广州能源研究所集成技术研发中心
通讯作者	Chen, Xinde
作者单位	1.Chinese Acad Sci, Key Lab Renewable Energy, 2 Nengyuan Rd, Guangzhou 510640, Guangdong, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, 2 Nengyuan Rd, Guangzhou 510640, Guangdong, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, R&D Ctr Xuyi Attapulgite Appl Technol, 3 Dongfeng Rd, Xuyi 211700, Peoples R China 4.Univ Chinese Acad Sci, 19A Yuquan Rd, Beijing 100049, Peoples R China
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Lin, Xiaoqing,Huang, Qianlin,Qi, Gaoxiang,et al. Estimation of fixed-bed column parameters and mathematical modeling of breakthrough behaviors for adsorption of levulinic acid from aqueous solution using SY-01 resin[J]. SEPARATION AND PURIFICATION TECHNOLOGY,2017,174:222-231.
APA	Lin, Xiaoqing.,Huang, Qianlin.,Qi, Gaoxiang.,Shi, Silan.,Xiong, Lian.,...&Chen, Xinde.(2017).Estimation of fixed-bed column parameters and mathematical modeling of breakthrough behaviors for adsorption of levulinic acid from aqueous solution using SY-01 resin.SEPARATION AND PURIFICATION TECHNOLOGY,174,222-231.
MLA	Lin, Xiaoqing,et al."Estimation of fixed-bed column parameters and mathematical modeling of breakthrough behaviors for adsorption of levulinic acid from aqueous solution using SY-01 resin".SEPARATION AND PURIFICATION TECHNOLOGY 174(2017):222-231.