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Estimation of fixed-bed column parameters and mathematical modeling of breakthrough behaviors for adsorption of levulinic acid from aqueous solution using SY-01 resin
Lin, Xiaoqing1,2,3; Huang, Qianlin2,4; Qi, Gaoxiang2,4; Shi, Silan2,4; Xiong, Lian1,2,3; Huang, Chao1,2,3; Chen, Xuefang1,2,3; Li, Hailong1,2,3; Chen, Xinde1,2,3
2017-03-01
发表期刊SEPARATION AND PURIFICATION TECHNOLOGY
卷号174页码:222-231
摘要Levulinic acid (LA) adsorption on a rnicroporous hyper-cross-linked adsorption resin, SY-01, from aqueous solution was performed in a fixed-bed column. Batch equilibrium isotherm was analyzed using Langmuir and Freundlich isotherm models, and the Langmuir isotherm model was found to fit the adsorption isotherm data well. The effects of feed flow rate (Q(f) = 1.0-5.0 mL/min), initial LA concentration (c(f) = 1.0-10.0 g/L), fixed-bed column length (L-c = 5.65-16.96 cm) and fixed-bed column diameter (D-c= 1.6-5.5 cm) on the adsorption characteristics of LA were investigated systematically. The results show that an increase in fixed-bed column length, fixed-bed column diameter, initial LA concentration and a decrease in feed flow rate improve the adsorption performance. Furthermore, a general rate model (GRM) was developed for predicting adsorption breakthrough curves of LA. The mathematical model results were in good agreement with the experimental data under various operating conditions, which confirmed that the GRM can successfully simulate this process. In addition, the values of Biot number (Bi) at different operating conditions were all more than 10, demonstrating intraparticle diffusion is the rate controlling step for the adsorption of LA on the resin. In conclusion, our results provide an important basis for future scale-up of the product recovery of LA from biomass hydrolysate. (C) 2016 Elsevier B.V. All rights reserved.
文章类型Article
关键词Levulinic Acid Fixed-bed Column Adsorption Breakthrough Curve Mathematical Model Resin Adsorbent
WOS标题词Science & Technology ; Technology
资助者Science and Technology Planning Project of Guangdong Province, China(2016A010104009 ; Project of National Natural Science Foundation of China(51508547 ; Youth Innovation Promotion Association, Chinese Academy of Sciences(2015290) ; Project of Natural Science Foundation of Guangdong Province(2016A030310124) ; Foundation of Director of Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences(y407r41001) ; 2016A010105016) ; 21606229 ; 31600475) ; Science and Technology Planning Project of Guangdong Province, China(2016A010104009 ; Project of National Natural Science Foundation of China(51508547 ; Youth Innovation Promotion Association, Chinese Academy of Sciences(2015290) ; Project of Natural Science Foundation of Guangdong Province(2016A030310124) ; Foundation of Director of Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences(y407r41001) ; 2016A010105016) ; 21606229 ; 31600475)
DOI10.1016/j.seppur.2016.10.016
研究领域[WOS]Engineering
关键词[WOS]PORE DIFFUSION-MODEL ; FERMENTATION BROTH ; POLYMERIC ADSORBENT ; MACROPOROUS RESIN ; ACTIVATED CARBON ; METHYLENE-BLUE ; PACKED-BEDS ; REMOVAL ; BUTANOL ; SEPARATION
收录类别SCI
语种英语
资助者Science and Technology Planning Project of Guangdong Province, China(2016A010104009 ; Project of National Natural Science Foundation of China(51508547 ; Youth Innovation Promotion Association, Chinese Academy of Sciences(2015290) ; Project of Natural Science Foundation of Guangdong Province(2016A030310124) ; Foundation of Director of Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences(y407r41001) ; 2016A010105016) ; 21606229 ; 31600475) ; Science and Technology Planning Project of Guangdong Province, China(2016A010104009 ; Project of National Natural Science Foundation of China(51508547 ; Youth Innovation Promotion Association, Chinese Academy of Sciences(2015290) ; Project of Natural Science Foundation of Guangdong Province(2016A030310124) ; Foundation of Director of Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences(y407r41001) ; 2016A010105016) ; 21606229 ; 31600475)
WOS类目Engineering, Chemical
WOS记录号WOS:000389091700027
引用统计
被引频次:8[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/13983
专题中国科学院广州能源研究所
集成技术研发中心
作者单位1.Chinese Acad Sci, Key Lab Renewable Energy, 2 Nengyuan Rd, Guangzhou 510640, Guangdong, Peoples R China
2.Chinese Acad Sci, Guangzhou Inst Energy Convers, 2 Nengyuan Rd, Guangzhou 510640, Guangdong, Peoples R China
3.Chinese Acad Sci, Guangzhou Inst Energy Convers, R&D Ctr Xuyi Attapulgite Appl Technol, 3 Dongfeng Rd, Xuyi 211700, Peoples R China
4.Univ Chinese Acad Sci, 19A Yuquan Rd, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Lin, Xiaoqing,Huang, Qianlin,Qi, Gaoxiang,et al. Estimation of fixed-bed column parameters and mathematical modeling of breakthrough behaviors for adsorption of levulinic acid from aqueous solution using SY-01 resin[J]. SEPARATION AND PURIFICATION TECHNOLOGY,2017,174:222-231.
APA Lin, Xiaoqing.,Huang, Qianlin.,Qi, Gaoxiang.,Shi, Silan.,Xiong, Lian.,...&Chen, Xinde.(2017).Estimation of fixed-bed column parameters and mathematical modeling of breakthrough behaviors for adsorption of levulinic acid from aqueous solution using SY-01 resin.SEPARATION AND PURIFICATION TECHNOLOGY,174,222-231.
MLA Lin, Xiaoqing,et al."Estimation of fixed-bed column parameters and mathematical modeling of breakthrough behaviors for adsorption of levulinic acid from aqueous solution using SY-01 resin".SEPARATION AND PURIFICATION TECHNOLOGY 174(2017):222-231.
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