Hydrodeoxygenation of Anisole over Ni/alpha-Al2O3 Catalyst

doi:10.1063/1674-0068/29/cjcp1603062

GIEC OpenIR > 中国科学院广州能源研究所

	Hydrodeoxygenation of Anisole over Ni/alpha-Al2O3 Catalyst
	Tang, Wen-wu 1,3; Zhang, Xing-hua2,3 ; Zhang, Qi2,3 ; Wang, Tie-jun2,3 ; Ma, Long-long2,3
	2016-10-01
发表期刊	CHINESE JOURNAL OF CHEMICAL PHYSICS
卷号	29 期号:5 页码:617-622
摘要	Ni-based catalysts supported on different supports (alpha-Al2O3, gamma-Al2O3, SiO2, TiO2, and ZrO2) were prepared by impregnation. Effects of supports on catalytic performance were tested using hydrodeoxygenation reaction (HDO) of anisole as model reaction. Ni/alpha-Al2O3 was found to be the highest active catalyst for HDO of anisole. Under the optimal conditions, the anisole conversion is 93.25% and the hydrocarbon yield is 90.47%. Catalyst characterization using H-2-TPD method demonstrates that Ni/alpha-Al2O3 catalyst possesses more amount of active metal Ni than those of other investigated catalysts, which can enhance the catalytic activity for hydrogenation. Furthermore, it is found that the Ni/alpha-Al2O3 catalyst has excellent repeatability, and the carbon deposited on the surface of catalyst is negligible.
文章类型	Article
关键词	Anisole Hydrodeoxygenation Ni/alpha-al2o3 Hydrocarbons
WOS标题词	Science & Technology ; Physical Sciences
DOI	10.1063/1674-0068/29/cjcp1603062
研究领域[WOS]	Physics
关键词[WOS]	LIGNIN DEPOLYMERIZATION ; PHENOLIC-COMPOUNDS ; AQUEOUS-PHASE ; BIO-OIL ; EFFICIENT ; GUAIACOL ; DECOMPOSITION ; HYDROCARBONS ; VALORIZATION ; CONVERSION
收录类别	SCI
语种	英语
项目资助者	National Natural Science Foundation of China(51576198) ; National Key Technology RD Program(2014BAD02B01) ; Youth Innovation Promotion Association of Chinese Academy of Sciences(2015288)
WOS类目	Physics, Atomic, Molecular & Chemical
WOS记录号	WOS:000388063400015
引用统计	被引频次：6[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/13975
专题	中国科学院广州能源研究所
作者单位	1.Univ Sci & Technol China, Dept Chem, Hefei 230026, Peoples R China 2.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Tang, Wen-wu,Zhang, Xing-hua,Zhang, Qi,et al. Hydrodeoxygenation of Anisole over Ni/alpha-Al2O3 Catalyst[J]. CHINESE JOURNAL OF CHEMICAL PHYSICS,2016,29(5):617-622.
APA	Tang, Wen-wu,Zhang, Xing-hua,Zhang, Qi,Wang, Tie-jun,&Ma, Long-long.(2016).Hydrodeoxygenation of Anisole over Ni/alpha-Al2O3 Catalyst.CHINESE JOURNAL OF CHEMICAL PHYSICS,29(5),617-622.
MLA	Tang, Wen-wu,et al."Hydrodeoxygenation of Anisole over Ni/alpha-Al2O3 Catalyst".CHINESE JOURNAL OF CHEMICAL PHYSICS 29.5(2016):617-622.