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Enhanced esterification of oleic acid and methanol by deep eutectic solvent assisted Amberlyst heterogeneous catalyst
Pan, Ying1,2; Alam, Md. Asraful1,4; Wang, Zhongming1,4; Wu, Jingcheng1,4; Zhang, Yi1,4; Yuan, Zhenhong1,3,4
2016-11-01
发表期刊BIORESOURCE TECHNOLOGY
卷号220页码:543-548
摘要In present study, esterification of oleic acid with methanol using deep eutectic solvent (DES) assisted Amberlyst heterogeneous catalyst was investigated to produce biodiesel. Results showed that esterification efficiency was enhanced by the DES. The combined effect of DES on Amberlyst BD20 (BD20) is better than Amberlyst 15 (A-15) due to different structure. The optimal reaction conditions were 12:1 M ratio of methanol to oleic acid, 20% (wt/wt) catalyst (BD20-DES (2:8) and A-15-DES (8:2)) at 85 degrees C for 100 min with agitating at 200 rpm. The mechanism involved in catalysis and their capacity to reuse were studied. We proposed, Choline chloride-glycerol (Chcl-gly) DES could enhance the Amberlyst function due to the hydrogen bond effect on both DES and water. BD20 has fewer pores than A-15, have desirable performance in decreasing the inhibition the water during esterification of high FFA content and provide better performance in reuse. (C) 2016 Elsevier Ltd. All rights reserved.
文章类型Article
关键词Amberlyst Heterogeneous Catalyst Deep Eutectic Solvent Oleic Acid Esterification Biodiesel
WOS标题词Science & Technology ; Life Sciences & Biomedicine ; Technology
资助者National Natural Science Foundation of China(51476177) ; National Natural Science Foundation for research team of Guangdong, China(2016A030312007) ; National Natural Science Foundation of China(51476177) ; National Natural Science Foundation for research team of Guangdong, China(2016A030312007)
DOI10.1016/j.biortech.2016.08.113
研究领域[WOS]Agriculture ; Biotechnology & Applied Microbiology ; Energy & Fuels
关键词[WOS]BIODIESEL PRODUCTION ; CHOLINE CHLORIDE ; OIL ; OPTIMIZATION ; KINETICS
收录类别SCI
语种英语
资助者National Natural Science Foundation of China(51476177) ; National Natural Science Foundation for research team of Guangdong, China(2016A030312007) ; National Natural Science Foundation of China(51476177) ; National Natural Science Foundation for research team of Guangdong, China(2016A030312007)
WOS类目Agricultural Engineering ; Biotechnology & Applied Microbiology ; Energy & Fuels
WOS记录号WOS:000384712900068
引用统计
被引频次:8[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/13948
专题中国科学院广州能源研究所
作者单位1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
2.Univ Sci & Technol China, Nano Sci & Technol Inst, Suzhou 215123, Peoples R China
3.Collaborat Innovat Ctr Biomass Energy, Zhengzhou 450002, Henan Province, Peoples R China
4.Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Guangdong, Peoples R China
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Pan, Ying,Alam, Md. Asraful,Wang, Zhongming,et al. Enhanced esterification of oleic acid and methanol by deep eutectic solvent assisted Amberlyst heterogeneous catalyst[J]. BIORESOURCE TECHNOLOGY,2016,220:543-548.
APA Pan, Ying,Alam, Md. Asraful,Wang, Zhongming,Wu, Jingcheng,Zhang, Yi,&Yuan, Zhenhong.(2016).Enhanced esterification of oleic acid and methanol by deep eutectic solvent assisted Amberlyst heterogeneous catalyst.BIORESOURCE TECHNOLOGY,220,543-548.
MLA Pan, Ying,et al."Enhanced esterification of oleic acid and methanol by deep eutectic solvent assisted Amberlyst heterogeneous catalyst".BIORESOURCE TECHNOLOGY 220(2016):543-548.
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