GIEC OpenIR  > 中国科学院广州能源研究所
Screening of NiFe2O4 Nanoparticles as Oxygen Carrier in Chemical Looping Hydrogen Production
Liu, Shuai1,2; He, Fang1; Huang, Zhen1; Zheng, Anqing1; Feng, Yipeng1; Shen, Yang1; Li, Haibin1; Wu, Hao3; Glarbore, Peter3
2016-05-01
Source PublicationENERGY & FUELS
Volume30Issue:5Pages:4251-4262
AbstractThe objective of this paper is to systematically investigate the influences of different preparation methods on the properties of NiFe2O4 nanoparticles as oxygen carrier in chemical looping hydrogen production (CLH). The solid state (SS), coprecipitation (CP), hydrothermal (HT), and sol-gel (SG) methods were used to prepare NiFe2O4 oxygen carriers. Samples were characterized by X-ray diffraction (XRD), Raman spectroscopy, scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), Brunauer-Emmett-Teller (BET) surface area measurement, as well as Barrett-Joyner-Halenda (BJH) porosity test. The performance of the prepared materials was first evaluated in a TGA reactor through a CO reduction and subsequent steam oxidation process. Then a complete redox process was conducted in a fixed-bed reactor, where the NiFe2O4 oxygen carrier was first reduced by simulated biomass pyrolysis gas (24% H-2 + 24% CO + 12% CO2 + N-2 balance), then reacted with steam to produce H-2, and finally fully oxidized by air. The NiFe2O4 oxygen carrier prepared by the sol gel method showed the best capacity for hydrogen production and the highest recovery degree of lattice oxygen, in agreement with the characterization results. Furthermore, compared to individual nickel ferrite particles, the mixture of NiFe2O4 and SiO2 presented remarkably higher stability during 20 cycles in the fixed-bed reactor. The structural and morphological stability of samples after reactions was also examined by XRD, XPS, and SEM analyses.
SubtypeArticle
WOS HeadingsScience & Technology ; Technology
DOI10.1021/acs.energyfuels.6b00284
WOS Subject ExtendedEnergy & Fuels ; Engineering
WOS KeywordNICKEL FERRITE NANOPARTICLES ; SOL-GEL METHOD ; MAGNETIC-PROPERTIES ; CATALYTIC-PROPERTIES ; PARTICLE-SIZE ; IRON-ORE ; COMBUSTION ; GASIFICATION ; METHANE ; BIOMASS
Indexed BySCI ; ISTP
Language英语
WOS SubjectEnergy & Fuels ; Engineering, Chemical
WOS IDWOS:000376417600076
Citation statistics
Cited Times:20[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/11444
Collection中国科学院广州能源研究所
Affiliation1.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
2.Univ Chinese Acad Sci, Sino Danish Ctr Educ & Res, Beijing 100049, Peoples R China
3.Tech Univ Denmark, Dept Chem & Biochem Engn, DK-2800 Lyngby, Denmark
First Author AffilicationGuangZhou Institute of Energy Conversion,Chinese Academy of Sciences
Recommended Citation
GB/T 7714
Liu, Shuai,He, Fang,Huang, Zhen,et al. Screening of NiFe2O4 Nanoparticles as Oxygen Carrier in Chemical Looping Hydrogen Production[J]. ENERGY & FUELS,2016,30(5):4251-4262.
APA Liu, Shuai.,He, Fang.,Huang, Zhen.,Zheng, Anqing.,Feng, Yipeng.,...&Glarbore, Peter.(2016).Screening of NiFe2O4 Nanoparticles as Oxygen Carrier in Chemical Looping Hydrogen Production.ENERGY & FUELS,30(5),4251-4262.
MLA Liu, Shuai,et al."Screening of NiFe2O4 Nanoparticles as Oxygen Carrier in Chemical Looping Hydrogen Production".ENERGY & FUELS 30.5(2016):4251-4262.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Liu, Shuai]'s Articles
[He, Fang]'s Articles
[Huang, Zhen]'s Articles
Baidu academic
Similar articles in Baidu academic
[Liu, Shuai]'s Articles
[He, Fang]'s Articles
[Huang, Zhen]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Liu, Shuai]'s Articles
[He, Fang]'s Articles
[Huang, Zhen]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.