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Advances in DMF and C-5/C-6 Alkanes Production from Lignocellulose
Yang Yue1,2; Liu Qiying1; Cai Chiliu1,3; Tan Jin1; Wang Tiejun1; Ma Longlong1,2
2016-03-01
发表期刊PROGRESS IN CHEMISTRY
卷号28期号:2-3页码:363-374
摘要Lignocellulosic biomass is an important renewable resource, and has potential application in high quality biofuels to substitute fossil energy and reduce green house gas emission. Among those high quality biofuels, oxygen-contained 2,5-dimethyl furan (DMF) and C-5/C-6 alkanes show particular interests because these two kinds fuels could be produced from biomass via 5-hydroxymethyl furfural (HMF) intermediate. DMF is an ideal replacement and/or dopant for the presently used gasoline by enhancing combustion efficiency and reducing contaminant emission because of its higher energy density, higher octane number and higher boiling point. On the other hand, C-5/C-6 alkanes are the important gasoline components for adjusting the octane number and volatile properties. In this paper, combining our studies, we systematically summarize the status-of-the-art technologies for HMF synthesis from cellulose, and DMF and C-5/C-6 alkanes production by selective and complete hydrodeoxygenation of HMF respectively, depended on reaction medium, catalyst and pathway. The reaction mediums include water, ionic liquid, polar aprotic organic solvent and water contained biphasic solvent; and catalysts include inorganic acid, metal salt, solid acid and supported catalyst. Finally, the future of biomass derived DMF and C-5/C-6 alkanes production is remarked and prospected.
文章类型Review
关键词Cellulose Dmf Hmf C-5/c-6 Alkane Catalyst Reaction Mechanism
WOS标题词Science & Technology ; Physical Sciences
DOI10.7536/PC150820
研究领域[WOS]Chemistry
关键词[WOS]LIQUID FUEL 2,5-DIMETHYLFURAN ; BIPHASIC SOLVENT SYSTEM ; CATALYTIC CONVERSION ; EFFICIENT PRODUCTION ; FURAN-DERIVATIVES ; IONIC LIQUIDS ; SOLID ACID ; NI/HZSM-5 CATALYSTS ; SUBCRITICAL WATER ; LEVULINIC ACID
收录类别SCI
语种英语
WOS类目Chemistry, Multidisciplinary
WOS记录号WOS:000374083300017
引用统计
被引频次:6[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/11231
专题中国科学院广州能源研究所
作者单位1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
2.Univ Sci & Technol China, Dept Chem, Hefei 230026, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
第一作者单位中国科学院广州能源研究所
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Yang Yue,Liu Qiying,Cai Chiliu,et al. Advances in DMF and C-5/C-6 Alkanes Production from Lignocellulose[J]. PROGRESS IN CHEMISTRY,2016,28(2-3):363-374.
APA Yang Yue,Liu Qiying,Cai Chiliu,Tan Jin,Wang Tiejun,&Ma Longlong.(2016).Advances in DMF and C-5/C-6 Alkanes Production from Lignocellulose.PROGRESS IN CHEMISTRY,28(2-3),363-374.
MLA Yang Yue,et al."Advances in DMF and C-5/C-6 Alkanes Production from Lignocellulose".PROGRESS IN CHEMISTRY 28.2-3(2016):363-374.
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