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Advances in DMF and C-5/C-6 Alkanes Production from Lignocellulose
Yang Yue1,2; Liu Qiying1; Cai Chiliu1,3; Tan Jin1; Wang Tiejun1; Ma Longlong1,2
2016-03-01
Source PublicationPROGRESS IN CHEMISTRY
Volume28Issue:2-3Pages:363-374
AbstractLignocellulosic biomass is an important renewable resource, and has potential application in high quality biofuels to substitute fossil energy and reduce green house gas emission. Among those high quality biofuels, oxygen-contained 2,5-dimethyl furan (DMF) and C-5/C-6 alkanes show particular interests because these two kinds fuels could be produced from biomass via 5-hydroxymethyl furfural (HMF) intermediate. DMF is an ideal replacement and/or dopant for the presently used gasoline by enhancing combustion efficiency and reducing contaminant emission because of its higher energy density, higher octane number and higher boiling point. On the other hand, C-5/C-6 alkanes are the important gasoline components for adjusting the octane number and volatile properties. In this paper, combining our studies, we systematically summarize the status-of-the-art technologies for HMF synthesis from cellulose, and DMF and C-5/C-6 alkanes production by selective and complete hydrodeoxygenation of HMF respectively, depended on reaction medium, catalyst and pathway. The reaction mediums include water, ionic liquid, polar aprotic organic solvent and water contained biphasic solvent; and catalysts include inorganic acid, metal salt, solid acid and supported catalyst. Finally, the future of biomass derived DMF and C-5/C-6 alkanes production is remarked and prospected.
SubtypeReview
KeywordCellulose Dmf Hmf C-5/c-6 Alkane Catalyst Reaction Mechanism
WOS HeadingsScience & Technology ; Physical Sciences
DOI10.7536/PC150820
WOS Subject ExtendedChemistry
WOS KeywordLIQUID FUEL 2,5-DIMETHYLFURAN ; BIPHASIC SOLVENT SYSTEM ; CATALYTIC CONVERSION ; EFFICIENT PRODUCTION ; FURAN-DERIVATIVES ; IONIC LIQUIDS ; SOLID ACID ; NI/HZSM-5 CATALYSTS ; SUBCRITICAL WATER ; LEVULINIC ACID
Indexed BySCI
Language英语
WOS SubjectChemistry, Multidisciplinary
WOS IDWOS:000374083300017
Citation statistics
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/11231
Collection中国科学院广州能源研究所
Affiliation1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
2.Univ Sci & Technol China, Dept Chem, Hefei 230026, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
First Author AffilicationGuangZhou Institute of Energy Conversion,Chinese Academy of Sciences
Recommended Citation
GB/T 7714
Yang Yue,Liu Qiying,Cai Chiliu,et al. Advances in DMF and C-5/C-6 Alkanes Production from Lignocellulose[J]. PROGRESS IN CHEMISTRY,2016,28(2-3):363-374.
APA Yang Yue,Liu Qiying,Cai Chiliu,Tan Jin,Wang Tiejun,&Ma Longlong.(2016).Advances in DMF and C-5/C-6 Alkanes Production from Lignocellulose.PROGRESS IN CHEMISTRY,28(2-3),363-374.
MLA Yang Yue,et al."Advances in DMF and C-5/C-6 Alkanes Production from Lignocellulose".PROGRESS IN CHEMISTRY 28.2-3(2016):363-374.
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