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Evaluation of multi-cycle performance of chemical looping dry reforming using CO2 as an oxidant with Fe-Ni bimetallic oxides
Huang, Zhen1; Jiang, Huanqi1; He, Fang2; Chen, Dezhen1; Wei, Guoqiang2; Zhao, Kun2; Zheng, Anqing2; Feng, Yipeng2; Zhao, Zengli2; Li, Haibin2
2016
发表期刊JOURNAL OF ENERGY CHEMISTRY
卷号25期号:1页码:62-70
摘要Chemical looping dry reforming (CLDR) is an innovative technology for CO2 utilization using the chemical looping principle. The CLDR process consists of three stages, i.e. CH4 reduction, CO2 reforming, and air oxidation. Spinel nickel ferrite (NiFe2O4) was prepared and its multi-cycle performance as an oxygen carrier for CLDR was experimentally investigated. X-ray diffraction (XRD) and Laser Raman spectroscopy showed that a pure spinel crystalline phase (NiFe2O4) was obtained by a parallel flow co-precipitating method. NiFe2O4 was reduced into Fe-Ni alloy and wustite (FexO) during the CH4 reduction process. Subsequent oxidation of the reduced oxygen carrier was performed with CO2 as an oxidant to form an intermediate state: a mixture of spinel Ni1-xFe2+xO4, Fe2+yO4 and metallic Ni. And CO was generated in parallel during this stage. Approximate 185 mL of CO was generated for 1 g spinel NiFe2O4 in a single cycle. The intermediate oxygen carrier was fully oxidized in the air oxidation stage to form a mixture of Ni1+xFe2-xO4 and Fe2O3. Although the original state of oxygen carrier (NiFe2O4) was not fully regenerated and agglomeration was observed, a good recyclability was shown in 10 successive redox cycles. (C) 2015 Science Press and Dalian Institute of Chemical Physics. All rights reserved.
文章类型Article
关键词Chemical Looping Oxygen Carrier Nickel Ferrite Co2 Utilization Multi-cycle Performance
WOS标题词Science & Technology ; Physical Sciences ; Technology
DOI10.1016/j.jechem.2015.10.008
研究领域[WOS]Chemistry ; Energy & Fuels ; Engineering
关键词[WOS]SYNTHESIS GAS-PRODUCTION ; OXYGEN CARRIER ; CARBON-DIOXIDE ; IRON-OXIDES ; COMBUSTION ; FERRITES ; DECOMPOSITION ; METHANE ; BIOMASS ; COAL
收录类别SCI
语种英语
WOS类目Chemistry, Applied ; Chemistry, Physical ; Energy & Fuels ; Engineering, Chemical
WOS记录号WOS:000373244400008
引用统计
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/11204
专题中国科学院广州能源研究所
作者单位1.Tongji Univ, Sch Mech & Engn, Thermal & Environm Engn Inst, Shanghai 201804, Peoples R China
2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
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Huang, Zhen,Jiang, Huanqi,He, Fang,et al. Evaluation of multi-cycle performance of chemical looping dry reforming using CO2 as an oxidant with Fe-Ni bimetallic oxides[J]. JOURNAL OF ENERGY CHEMISTRY,2016,25(1):62-70.
APA Huang, Zhen.,Jiang, Huanqi.,He, Fang.,Chen, Dezhen.,Wei, Guoqiang.,...&Li, Haibin.(2016).Evaluation of multi-cycle performance of chemical looping dry reforming using CO2 as an oxidant with Fe-Ni bimetallic oxides.JOURNAL OF ENERGY CHEMISTRY,25(1),62-70.
MLA Huang, Zhen,et al."Evaluation of multi-cycle performance of chemical looping dry reforming using CO2 as an oxidant with Fe-Ni bimetallic oxides".JOURNAL OF ENERGY CHEMISTRY 25.1(2016):62-70.
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