Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| Preparation and characterization of epoxidized microbial oil | |
Yang, Dan1,2; Xiong, Lian1,2 ; Wang, Bo2,3; Chen, Xuefang1,2; Wang, Can1,2; Huang, Chao1,2; Zhang, Hairong1,2; Guo, Haijun1,2; Chen, Xinde1,2
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| 2016-03-01 | |
| Source Publication | KOREAN JOURNAL OF CHEMICAL ENGINEERING
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| Volume | 33Issue:3Pages:964-971 |
| Abstract | The potential of microbial oil derived from yeasts through fermentation using crops biomass for the formation of plasticizers was investigated. Plasticizers were formed via epoxidation reaction. Five factors of the orthogonal experiment (reaction temperature, time, weight ratio of H2O2/MO, H2SO4/MO, and HCOOH/MO) have been used for optimization of parameters. To further enhance the iodine value of microbial oil and increase the epoxy value of the epoxide, an amount of soybean oil was added. The products were characterized by FTIR, C-13-NMR and H-1-NMR. Under the optimum condition, the epoxy value and the iodine value of epoxide product were 6.21% and 1.8 g I-2/100 g with a yield of 91.86% at an oil conversion of 98.43%. This study successfully demonstrated the conversion of crops biomass into value-added chemicals using simple and conventional chemical reactions. |
| Subtype | Article |
| Keyword | Microbial Oil Plasticizer Iodine Values Epoxy Value Crops Biomass |
| WOS Headings | Science & Technology ; Physical Sciences ; Technology |
| DOI | 10.1007/s11814-015-0216-6 |
| WOS Subject Extended | Chemistry ; Engineering |
| WOS Keyword | CORNCOB ACID HYDROLYSATE ; SOYBEAN-OIL ; BIODIESEL PRODUCTION ; CANOLA OIL ; SEED OILS ; EPOXIDATION ; KINETICS ; POLYOL ; WASTE |
| Indexed By | SCI |
| Language | 英语 |
| WOS Subject | Chemistry, Multidisciplinary ; Engineering, Chemical |
| WOS ID | WOS:000371795000028 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/11131 |
| Collection | 中国科学院广州能源研究所 集成技术研发中心 |
| Affiliation | 1.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 3.Grad Univ Chinese Acad Sci, Beijing 10049, Peoples R China |
| First Author Affilication | GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences |
| Recommended Citation GB/T 7714 | Yang, Dan,Xiong, Lian,Wang, Bo,et al. Preparation and characterization of epoxidized microbial oil[J]. KOREAN JOURNAL OF CHEMICAL ENGINEERING,2016,33(3):964-971. |
| APA | Yang, Dan.,Xiong, Lian.,Wang, Bo.,Chen, Xuefang.,Wang, Can.,...&Chen, Xinde.(2016).Preparation and characterization of epoxidized microbial oil.KOREAN JOURNAL OF CHEMICAL ENGINEERING,33(3),964-971. |
| MLA | Yang, Dan,et al."Preparation and characterization of epoxidized microbial oil".KOREAN JOURNAL OF CHEMICAL ENGINEERING 33.3(2016):964-971. |
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