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Preparation and characterization of epoxidized microbial oil
Yang, Dan1,2; Xiong, Lian1,2; Wang, Bo2,3; Chen, Xuefang1,2; Wang, Can1,2; Huang, Chao1,2; Zhang, Hairong1,2; Guo, Haijun1,2; Chen, Xinde1,2
2016-03-01
发表期刊KOREAN JOURNAL OF CHEMICAL ENGINEERING
卷号33期号:3页码:964-971
摘要The potential of microbial oil derived from yeasts through fermentation using crops biomass for the formation of plasticizers was investigated. Plasticizers were formed via epoxidation reaction. Five factors of the orthogonal experiment (reaction temperature, time, weight ratio of H2O2/MO, H2SO4/MO, and HCOOH/MO) have been used for optimization of parameters. To further enhance the iodine value of microbial oil and increase the epoxy value of the epoxide, an amount of soybean oil was added. The products were characterized by FTIR, C-13-NMR and H-1-NMR. Under the optimum condition, the epoxy value and the iodine value of epoxide product were 6.21% and 1.8 g I-2/100 g with a yield of 91.86% at an oil conversion of 98.43%. This study successfully demonstrated the conversion of crops biomass into value-added chemicals using simple and conventional chemical reactions.
文章类型Article
关键词Microbial Oil Plasticizer Iodine Values Epoxy Value Crops Biomass
WOS标题词Science & Technology ; Physical Sciences ; Technology
DOI10.1007/s11814-015-0216-6
研究领域[WOS]Chemistry ; Engineering
关键词[WOS]CORNCOB ACID HYDROLYSATE ; SOYBEAN-OIL ; BIODIESEL PRODUCTION ; CANOLA OIL ; SEED OILS ; EPOXIDATION ; KINETICS ; POLYOL ; WASTE
收录类别SCI
语种英语
WOS类目Chemistry, Multidisciplinary ; Engineering, Chemical
WOS记录号WOS:000371795000028
引用统计
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/11131
专题中国科学院广州能源研究所
集成技术研发中心
作者单位1.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China
3.Grad Univ Chinese Acad Sci, Beijing 10049, Peoples R China
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Yang, Dan,Xiong, Lian,Wang, Bo,et al. Preparation and characterization of epoxidized microbial oil[J]. KOREAN JOURNAL OF CHEMICAL ENGINEERING,2016,33(3):964-971.
APA Yang, Dan.,Xiong, Lian.,Wang, Bo.,Chen, Xuefang.,Wang, Can.,...&Chen, Xinde.(2016).Preparation and characterization of epoxidized microbial oil.KOREAN JOURNAL OF CHEMICAL ENGINEERING,33(3),964-971.
MLA Yang, Dan,et al."Preparation and characterization of epoxidized microbial oil".KOREAN JOURNAL OF CHEMICAL ENGINEERING 33.3(2016):964-971.
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