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Preparation and characterization of epoxidized microbial oil
Yang, Dan1,2; Xiong, Lian1,2; Wang, Bo2,3; Chen, Xuefang1,2; Wang, Can1,2; Huang, Chao1,2; Zhang, Hairong1,2; Guo, Haijun1,2; Chen, Xinde1,2
2016-03-01
Source PublicationKOREAN JOURNAL OF CHEMICAL ENGINEERING
Volume33Issue:3Pages:964-971
AbstractThe potential of microbial oil derived from yeasts through fermentation using crops biomass for the formation of plasticizers was investigated. Plasticizers were formed via epoxidation reaction. Five factors of the orthogonal experiment (reaction temperature, time, weight ratio of H2O2/MO, H2SO4/MO, and HCOOH/MO) have been used for optimization of parameters. To further enhance the iodine value of microbial oil and increase the epoxy value of the epoxide, an amount of soybean oil was added. The products were characterized by FTIR, C-13-NMR and H-1-NMR. Under the optimum condition, the epoxy value and the iodine value of epoxide product were 6.21% and 1.8 g I-2/100 g with a yield of 91.86% at an oil conversion of 98.43%. This study successfully demonstrated the conversion of crops biomass into value-added chemicals using simple and conventional chemical reactions.
SubtypeArticle
KeywordMicrobial Oil Plasticizer Iodine Values Epoxy Value Crops Biomass
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
DOI10.1007/s11814-015-0216-6
WOS Subject ExtendedChemistry ; Engineering
WOS KeywordCORNCOB ACID HYDROLYSATE ; SOYBEAN-OIL ; BIODIESEL PRODUCTION ; CANOLA OIL ; SEED OILS ; EPOXIDATION ; KINETICS ; POLYOL ; WASTE
Indexed BySCI
Language英语
WOS SubjectChemistry, Multidisciplinary ; Engineering, Chemical
WOS IDWOS:000371795000028
Citation statistics
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/11131
Collection中国科学院广州能源研究所
集成技术研发中心
Affiliation1.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China
3.Grad Univ Chinese Acad Sci, Beijing 10049, Peoples R China
First Author AffilicationGuangZhou Institute of Energy Conversion,Chinese Academy of Sciences
Recommended Citation
GB/T 7714
Yang, Dan,Xiong, Lian,Wang, Bo,et al. Preparation and characterization of epoxidized microbial oil[J]. KOREAN JOURNAL OF CHEMICAL ENGINEERING,2016,33(3):964-971.
APA Yang, Dan.,Xiong, Lian.,Wang, Bo.,Chen, Xuefang.,Wang, Can.,...&Chen, Xinde.(2016).Preparation and characterization of epoxidized microbial oil.KOREAN JOURNAL OF CHEMICAL ENGINEERING,33(3),964-971.
MLA Yang, Dan,et al."Preparation and characterization of epoxidized microbial oil".KOREAN JOURNAL OF CHEMICAL ENGINEERING 33.3(2016):964-971.
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