Active and regioselective rhodium catalyst supported on reduced graphene oxide for 1-hexene hydroformylation

doi:10.1039/c5cy01355k

GIEC OpenIR > 中国科学院广州能源研究所

	Active and regioselective rhodium catalyst supported on reduced graphene oxide for 1-hexene hydroformylation
	Tan, Minghui 1,2; Yang, Guohui 2; Wang, Tiejun4 ; Vitidsant, Tharapong 5; Li, Jie2 ; Wei, Qinhong 2; Ai, Peipei 2; Wu, Mingbo 1; Zheng, Jingtang 1; Tsubaki, Noritatsu 2,3
	2016
发表期刊	CATALYSIS SCIENCE & TECHNOLOGY
卷号	6 期号:4 页码:1162-1172
摘要	Alkene hydroformylation with syngas (CO + H-2) to produce aldehydes is one of the most important chemical reactions. However, designing heterogeneous catalysts to realize comparable performance with mature homogeneous catalysts is challenging. In this report, a reduced graphene oxide (RGO) supported rhodium nanoparticle (Rh/RGO) catalyst was successfully prepared via a one-pot liquid-phase reduction method and first applied in 1-hexene hydroformylation. 1-Hexene hydroformylation reaction under different reaction conditions with this Rh/RGO catalyst was investigated in detail. Low reaction temperature and short reaction time effectively enhanced the n/i (normal to iso) ratio of heptanal in the products. The catalytic performance of the Rh/RGO catalyst was also compared with those of Rh supported on other carbon materials, including activated carbon and carbon nanotubes (Rh/AC and Rh/CNTs). The results showed that the Rh/RGO catalyst exhibited the highest 1-hexene conversion and the largest n/i ratio of 4.0 among the tested catalysts. The special 2D nanosheet structure of the Rh/RGO catalyst, rather than the 3D porous and 1D nanotube structures of Rh/AC and Rh/CNTs, respectively, principally contributed to its excellent catalytic performance. These findings disclosed that reduced graphene oxide could be a promising catalyst support for designing heterogeneous hydroformylation catalysts.
文章类型	Article
WOS标题词	Science & Technology ; Physical Sciences
DOI	10.1039/c5cy01355k
研究领域[WOS]	Chemistry
关键词[WOS]	PARTIAL HYDROGENATION ; RAMAN-SPECTROSCOPY ; CARBON ; RH ; CONVERSION ; SPECTRA ; STYRENE ; OLEFINS ; TPR
收录类别	SCI
语种	英语
WOS类目	Chemistry, Physical
WOS记录号	WOS:000371177100024
引用统计	被引频次：43[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/11126
专题	中国科学院广州能源研究所
作者单位	1.China Univ Petr, State Key Lab Heavy Oil Proc, Qingdao 266580, Peoples R China 2.Toyama Univ, Sch Engn, Dept Appl Chem, Gofuku 3190, Toyama 9308555, Japan 3.JST, CREST, Chiyoda Ku, Gobancho 7, Tokyo 1020076, Japan 4.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 5.Chulalongkorn Univ, Dept Chem Technol, Fac Sci, Bangkok 10330, Thailand
推荐引用方式 GB/T 7714	Tan, Minghui,Yang, Guohui,Wang, Tiejun,et al. Active and regioselective rhodium catalyst supported on reduced graphene oxide for 1-hexene hydroformylation[J]. CATALYSIS SCIENCE & TECHNOLOGY,2016,6(4):1162-1172.
APA	Tan, Minghui.,Yang, Guohui.,Wang, Tiejun.,Vitidsant, Tharapong.,Li, Jie.,...&Tsubaki, Noritatsu.(2016).Active and regioselective rhodium catalyst supported on reduced graphene oxide for 1-hexene hydroformylation.CATALYSIS SCIENCE & TECHNOLOGY,6(4),1162-1172.
MLA	Tan, Minghui,et al."Active and regioselective rhodium catalyst supported on reduced graphene oxide for 1-hexene hydroformylation".CATALYSIS SCIENCE & TECHNOLOGY 6.4(2016):1162-1172.