Jet-Fuel Range Hydrocarbons from Biomass-Derived Sorbitol over Ni-HZSM-5/SBA-15 Catalyst

doi:10.3390/catal5042147

GIEC OpenIR > 中国科学院广州能源研究所

	Jet-Fuel Range Hydrocarbons from Biomass-Derived Sorbitol over Ni-HZSM-5/SBA-15 Catalyst
	Weng, Yujing 1,2; Qiu, Songbai 1; Ma, Longlong1 ; Liu, Qiying1 ; Ding, Mingyue1 ; Zhang, Qian 1,2; Zhang, Qi1 ; Wang, Tiejun1
	2015-12-01
发表期刊	CATALYSTS
卷号	5 期号:4 页码:2147-2160
摘要	Aromatics and cyclic-hydrocarbons are the significant components of jet fuel with high energy-density. However, conventional technologies for bio-fuel production cannot produce these products without further aromatization and isomerization. In this work, renewable liquid fuel with high content of aromatics and cyclic-hydrocarbons was obtained through aqueous catalytic conversion of biomass sorbitol over Ni-HZSM-5/SBA-15 catalyst. Texture characteristics of the catalyst were determined by physisorption of N-2, which indicated its bimodal pore structures were microporous (HZSM-5, pore width: 0.56 nm) and mesoporous (SBA-15, pore width: 8 nm). The surface acidity included weak and strong acid sites, predominantly Lewis type, and was further confirmed by the NH3-TPD and Py-IR analysis. The catalytic performances were tested in a fixed-bed reactor under the conditions of 593 K, WHSV of 0.75 h(-1), GHSV of 2500 h(-1) and 4.0 MPa of hydrogen pressure, whereby oil yield of 40.4 wt. % with aromatics and cyclic-hydrocarbons content of 80.0% was obtained.
文章类型	Article
关键词	Sorbitol Aromatic Cyclic-hydrocarbon Long-chain Alkane Aqueous Catalysis
WOS标题词	Science & Technology ; Physical Sciences
DOI	10.3390/catal5042147
研究领域[WOS]	Chemistry
关键词[WOS]	NI/HZSM-5 CATALYSTS ; PRODUCT DISTRIBUTION ; CO-IMPREGNATION ; ALKYL-AROMATICS ; CONVERSION ; TRANSFORMATION ; GASOLINE ; GLYCEROL ; METHANOL ; ZEOLITE
收录类别	SCI
语种	英语
WOS类目	Chemistry, Physical
WOS记录号	WOS:000367535300034
引用统计	被引频次：56[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/10939
专题	中国科学院广州能源研究所
作者单位	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Weng, Yujing,Qiu, Songbai,Ma, Longlong,et al. Jet-Fuel Range Hydrocarbons from Biomass-Derived Sorbitol over Ni-HZSM-5/SBA-15 Catalyst[J]. CATALYSTS,2015,5(4):2147-2160.
APA	Weng, Yujing.,Qiu, Songbai.,Ma, Longlong.,Liu, Qiying.,Ding, Mingyue.,...&Wang, Tiejun.(2015).Jet-Fuel Range Hydrocarbons from Biomass-Derived Sorbitol over Ni-HZSM-5/SBA-15 Catalyst.CATALYSTS,5(4),2147-2160.
MLA	Weng, Yujing,et al."Jet-Fuel Range Hydrocarbons from Biomass-Derived Sorbitol over Ni-HZSM-5/SBA-15 Catalyst".CATALYSTS 5.4(2015):2147-2160.