Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
Phase Equilibria and Dissociation Enthalpies of Methane Hydrate in Imidazolium Ionic Liquid Aqueous Solutions | |
Long, Zhen1; Zhou, Xuebing1,2; Shen, Xiaodong1; Li, Dongliang1; Liang, Deqing1 | |
2015-11-25 | |
发表期刊 | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH |
卷号 | 54期号:46页码:11701-11708 |
摘要 | This paper reports the thermodynamic inhibition effect of seven ionic liquids (ILs) on methane hydrate formation. The isochoric multistep heating dissociation pressure search method is applied for experimentally determining the phase boundary between hydrate-liquid-vapor (H-L-V) phases and liquid-vapor (L-V) phases in the pressure and temperature ranges of 3.45-13.28 MPa and 274.3-287.6 K, respectively. All the studied IL aqueous solutions are used at a mass fraction of 0.1. A comparison of the thermodynamic inhibitory performance of various ILs is carried out and reveals the predominant role of the type of anion of ILs. Considering the difficulty in directly measuring the dissociation enthalpies, the values of Delta H of methane hydrate are also calculated using the Clausius-Clapeyron equation. It is found that the mean dissociation enthalpies of methane hydrate in the presence of the seven ILs vary from 59.05 to 60.81 kJ.mol(1), and are very close to that in pure water. |
文章类型 | Article |
WOS标题词 | Science & Technology ; Technology |
DOI | 10.1021/acs.iecr.5b03480 |
研究领域[WOS] | Engineering |
关键词[WOS] | DUAL FUNCTION INHIBITORS ; MINE VENTILATION AIR ; EQUATION-OF-STATE ; CARBON-DIOXIDE ; NATURAL-GAS ; HYDROGEN-SULFIDE ; CLATHRATE ; PERFORMANCE ; ENRICHMENT ; MIXTURES |
收录类别 | SCI |
语种 | 英语 |
WOS类目 | Engineering, Chemical |
WOS记录号 | WOS:000366005200018 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.giec.ac.cn/handle/344007/10922 |
专题 | 中国科学院广州能源研究所 |
作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Gas Hydrate, Guangzhou 510640, Guangdong, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
第一作者单位 | 中国科学院广州能源研究所 |
推荐引用方式 GB/T 7714 | Long, Zhen,Zhou, Xuebing,Shen, Xiaodong,et al. Phase Equilibria and Dissociation Enthalpies of Methane Hydrate in Imidazolium Ionic Liquid Aqueous Solutions[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2015,54(46):11701-11708. |
APA | Long, Zhen,Zhou, Xuebing,Shen, Xiaodong,Li, Dongliang,&Liang, Deqing.(2015).Phase Equilibria and Dissociation Enthalpies of Methane Hydrate in Imidazolium Ionic Liquid Aqueous Solutions.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,54(46),11701-11708. |
MLA | Long, Zhen,et al."Phase Equilibria and Dissociation Enthalpies of Methane Hydrate in Imidazolium Ionic Liquid Aqueous Solutions".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 54.46(2015):11701-11708. |
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