Investigation on the structural effect of lignin during the hydrogenolysis process

doi:10.1016/j.biortech.2015.09.112

GIEC OpenIR > 中国科学院广州能源研究所

	Investigation on the structural effect of lignin during the hydrogenolysis process
	Shu, Riyang 1,2; Long, Jinxing 1; Xu, Ying1 ; Ma, Longlong1 ; Zhang, Qi1 ; Wang, Tiejun1 ; Wang, Chenguang 1; Yuan, Zhengqiu 1,2; Wu, Qingyun 1
	2016
发表期刊	BIORESOURCE TECHNOLOGY
卷号	200 页码:14-22
摘要	Structure has a significant effect on the lignin degradation, so the investigation of structural effect on the lignin depolymerization is important and imperative. In this study, hydrogenolysis of three typical lignins with different structures, dealkaline lignin, sodium lignosulfonate and organosolv lignin, was intensively compared over the synergistic catalyst of CrCl3 and Pd/C. The effects of reaction temperature, time, hydrogen pressure and catalyst dosage on the catalytic performance of lignin species were investigated. The structure evolution of lignins during the hydrogenolysis process was also compared. The results showed that organosolv lignin was more sensitive for hydrogenolysis than others due to its high unsaturation degree and low molecular weight. Further analysis indicated that the hydrogenolysis, hydrodeoxygenation and repolymerization reactions took place and competed intensely. Wherein, the depolymerization products with unsaturated carbonyl groups were prone to repolymerize. And the methylation was helpful to stabilize the depolymerization products and suppress the further repolymerization. (C) 2015 Elsevier Ltd. All rights reserved.
文章类型	Article
关键词	Lignin Hydrogenolysis Structure Repolymerization Methylation
WOS标题词	Science & Technology ; Life Sciences & Biomedicine ; Technology
DOI	10.1016/j.biortech.2015.09.112
研究领域[WOS]	Agriculture ; Biotechnology & Applied Microbiology ; Energy & Fuels
关键词[WOS]	CATALYTIC DEPOLYMERIZATION ; SUPERCRITICAL WATER ; FORMIC-ACID ; CHEMICALS ; EFFICIENT ; HYDRODEOXYGENATION ; HYDROGENATION ; VALORIZATION ; DEGRADATION ; CONVERSION
收录类别	SCI
语种	英语
WOS类目	Agricultural Engineering ; Biotechnology & Applied Microbiology ; Energy & Fuels
WOS记录号	WOS:000365811200003
引用统计	被引频次：116[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/10915
专题	中国科学院广州能源研究所
作者单位	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Shu, Riyang,Long, Jinxing,Xu, Ying,et al. Investigation on the structural effect of lignin during the hydrogenolysis process[J]. BIORESOURCE TECHNOLOGY,2016,200:14-22.
APA	Shu, Riyang.,Long, Jinxing.,Xu, Ying.,Ma, Longlong.,Zhang, Qi.,...&Wu, Qingyun.(2016).Investigation on the structural effect of lignin during the hydrogenolysis process.BIORESOURCE TECHNOLOGY,200,14-22.
MLA	Shu, Riyang,et al."Investigation on the structural effect of lignin during the hydrogenolysis process".BIORESOURCE TECHNOLOGY 200(2016):14-22.