Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
Laser Raman Spectroscopy and Its Application in Gas Hydrate Studies | |
Fu Juan1,2,5; Wu Neng-you2,4; Lu Hai-long3; Wu Dai-dai2; Su Qiu-cheng2 | |
2015-11-01 | |
Source Publication | SPECTROSCOPY AND SPECTRAL ANALYSIS |
Volume | 35Issue:11 |
Abstract | Gas hydrates are important potential energy resources. Microstructural characterization of gas hydrate can provide information to study the mechanism of gas hydrate formation and to support the exploitation and application of gas hydrate technology. This article systemly introduces the basic principle of laser Raman spectroscopy and summarizes its application in gas hydrate studies. Based on Raman results, not only can the information about gas composition and structural type be deduced, but also the occupancies of large and small cages and even hydration number can be calculated from the relative intensities of Raman peaks. By using the in-situ analytical technology, laser Raman specstropy can be applied to characterize the formation and decomposition processes of gas hydrate at microscale, for example the enclathration and leaving of gas molecules into/from its cages, to monitor the changes in gas concentration and gas solubility during hydrate formation and decomposition, and to identify phase changes in the study system. Laser Raman in-situ analytical technology has also been used in determination of hydrate structure and understanding its changing process under the conditions of ultra high pressure. Deep-sea in-situ Raman spectrometer can be employed for the in-situ analysis of the structures of natural gas hydrate and their formation environment. Raman imaging technology can be applied to specify the characteristics of crystallization and gas distribution over hydrate surface. With the development of laser Raman technology and its combination with other instruments, it will become more powerful and play a more significant role in the microscopic study of gas hydrate. |
Subtype | Article |
Keyword | Laser Raman Gas Hydrate In-situ Analysis Raman Imaging |
WOS Headings | Science & Technology ; Technology |
DOI | 10.3964/j.issn.1000-0593(2015)11-2996-07 |
WOS Subject Extended | Spectroscopy |
WOS Keyword | METHANE HYDRATE ; OCEAN ; DISSOCIATION ; NUMBER ; WATER |
Indexed By | SCI |
Language | 英语 |
WOS Subject | Spectroscopy |
WOS ID | WOS:000364503600004 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.giec.ac.cn/handle/344007/10898 |
Collection | 中国科学院广州能源研究所 |
Affiliation | 1.Chinese Acad Sci, Guangzhou Inst Geochem, Guangzhou 510640, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 3.Peking Univ, Coll Engn, Beijing 100871, Peoples R China 4.Qingdao Inst Marine Geol, Qingdao 266071, Peoples R China 5.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
First Author Affilication | GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences |
Recommended Citation GB/T 7714 | Fu Juan,Wu Neng-you,Lu Hai-long,et al. Laser Raman Spectroscopy and Its Application in Gas Hydrate Studies[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS,2015,35(11). |
APA | Fu Juan,Wu Neng-you,Lu Hai-long,Wu Dai-dai,&Su Qiu-cheng.(2015).Laser Raman Spectroscopy and Its Application in Gas Hydrate Studies.SPECTROSCOPY AND SPECTRAL ANALYSIS,35(11). |
MLA | Fu Juan,et al."Laser Raman Spectroscopy and Its Application in Gas Hydrate Studies".SPECTROSCOPY AND SPECTRAL ANALYSIS 35.11(2015). |
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