GIEC OpenIR  > 中国科学院广州能源研究所
In situ hydrogenation of furfural with additives over a RANEY (R) Ni catalyst
Xu, Ying1; Qiu, Songbai1; Long, Jinxing1; Wang, Chenguang1; Chang, Jiamin1,2,3; Tan, Jin1; Liu, Qiying1; Ma, Longlong1; Wang, Tiejun1; Zhang, Qi1
2015
发表期刊RSC Advances
卷号5期号:111
摘要The hydrogenation of furfural was studied over a RANEY (R) Ni catalyst (RN) under a N-2 atmosphere in water. Methanol, as a hydrogen donor, was used for hydrogenation via a reforming reaction. Additives, including acetone, acetic acid and phenol, were deliberately added in the in situ hydrogenation process of furfural to investigate the effect and interaction between two kinds of compounds. The results showed that the conversion of furfural decreased to some extent and the product distribution changed a lot because of second additives. Furfuryl alcohol (FA) was detected in the products in the presence of additives and was not detected when furfural was a single reactant. The selectivity of FA reached its highest degree of 19.01% with the addition of acetic acid. The addition of acetone promoted the decarboxylation reaction of furfural, and the selectivity of tetrahydrofurfuryl alcohol increased from 24.53% to 38.07%. The addition of phenol enhanced the rearrangement reaction of furfural and the selectivity of the five-membered ring increased from 47.99% to 88.76%. Compared with the in situ hydrogenation of the single reactant, the conversion of acetone increased and the conversion of acetic acid and phenol decreased in the presence of furfural. The reaction pathway of the hydrogenation of furfural is also discussed in this paper.
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
DOI10.1039/c5ra12844g
研究领域[WOS]Chemistry
关键词[WOS]BIO-OIL ; SELECTIVE CONVERSION ; MODEL COMPOUNDS ; PD CATALYSTS ; ACETIC-ACID ; CYCLOPENTANONE ; HYDRODEOXYGENATION ; ALCOHOL ; PYROLYSIS ; MECHANISM
收录类别SCI
语种英语
WOS类目Chemistry, Multidisciplinary
WOS记录号WOS:000364057000014
引用统计
被引频次:16[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/10896
专题中国科学院广州能源研究所
作者单位1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
2.Tianjin Univ, Fac Environm Sci & Engn, Tianjin 300072, Peoples R China
3.Tianjin Univ, State Key Lab Int Combust Engine, Tianjin 300072, Peoples R China
推荐引用方式
GB/T 7714
Xu, Ying,Qiu, Songbai,Long, Jinxing,et al. In situ hydrogenation of furfural with additives over a RANEY (R) Ni catalyst[J]. RSC Advances,2015,5(111).
APA Xu, Ying.,Qiu, Songbai.,Long, Jinxing.,Wang, Chenguang.,Chang, Jiamin.,...&Zhang, Qi.(2015).In situ hydrogenation of furfural with additives over a RANEY (R) Ni catalyst.RSC Advances,5(111).
MLA Xu, Ying,et al."In situ hydrogenation of furfural with additives over a RANEY (R) Ni catalyst".RSC Advances 5.111(2015).
条目包含的文件
条目无相关文件。
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Xu, Ying]的文章
[Qiu, Songbai]的文章
[Long, Jinxing]的文章
百度学术
百度学术中相似的文章
[Xu, Ying]的文章
[Qiu, Songbai]的文章
[Long, Jinxing]的文章
必应学术
必应学术中相似的文章
[Xu, Ying]的文章
[Qiu, Songbai]的文章
[Long, Jinxing]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。