Photoluminescence and cathodoluminescence properties of Li+ doped Gd1.88Eu0.12O3

doi:10.2109/jcersj2.123.989

GIEC OpenIR > 中国科学院广州能源研究所

	Photoluminescence and cathodoluminescence properties of Li+ doped Gd1.88Eu0.12O3
	Kang, Yipu 1; Shimokawa, Yohei 1; Ishihara, Yasutaka 1; Tsuji, Hitoshi 2; Hashimoto, Shinobu 3; Miao, Lei 4; Sakae, Tanemura 4; Iwamoto, Yuji 1
	2015-10-01
发表期刊	JOURNAL OF THE CERAMIC SOCIETY OF JAPAN
卷号	123 期号:1442 页码:989-994
摘要	Li+-doped cubic Gd1.88Eu0.12O3 phosphors were synthesized at 1200 degrees C in air by co-precipitation (CP) and solid state reaction (SS) methods. X-ray diffraction analysis revealed that, regardless of synthetic method, the average crystallite size for Li+-free Gd1.88Eu0.12O3 was approximately 400 nm, then increased with the amount of Li+ and at 20 mol%, reached about 2.3 mu m. Under excitation of the charge transfer band of Eu3+ at 245 nm, Gd1.88Eu0.12O3 exhibited a dominant photoluminescence (PL) red emission peak at 611 nm assigned to the electric dipole transition D-5(0) -> F-7(2) of Eu3+. The red emission peak intensity increased consistently with the amount of Li+-doping, while CP method was found to be effective in improving the red emission intensity at lower amounts of L-i+-doping from 0 to 8 mol%. Cathodoluminescence (CL) property was studied by mounting the synthesized phosphor on a vacuum fluorescent display (VFD) operated at an anode voltage of 50V. The Gd1.88Eu0.12O3 exhibited a similar spectrum with an intense red emission peak at 611 nm, and the highest luminance intensity for the CL red emission was achieved for 8 mol% Li+-doped Gd1.88Eu0.12O3 synthesized by SS method. The evaluation results of PL and CL properties suggested that, besides the crystallite size of Gd1.88Eu0.12O3, dispersion property of Eu3+ ions in the host Gd2O3 was an important factor for improving luminescent properties of Gd1.88Eu0.12O3. Moreover, under the present VFD operating condition at the low excitation voltage, it was thought to be essential for improving CL emission intensity to maintain a sufficient surface area of Gd1.88Eu0.12O3. (C)2015 The Ceramic Society of Japan. All rights reserved.
文章类型	Article
关键词	Gd2o3:Eu3++:Li++ Photoluminescence Cathodoluminescence Dispersion Property Crystallite Size Specific Surface Area
WOS标题词	Science & Technology ; Technology
DOI	10.2109/jcersj2.123.989
研究领域[WOS]	Materials Science
关键词[WOS]	FIELD-EMISSION DISPLAYS ; LUMINESCENCE PROPERTIES ; PHOSPHORS ; GD2O3-EU3+ ; DEGRADATION ; PARTICLES ; FILMS
收录类别	SCI
语种	英语
WOS类目	Materials Science, Ceramics
WOS记录号	WOS:000362506300011
引用统计
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/10872
专题	中国科学院广州能源研究所
作者单位	1.Nagoya Inst Technol, Grad Sch Engn, Dept Frontier Mat, Showa Ku, Nagoya, Aichi 4668555, Japan 2.Noritake Itron Corp, R&D Dept, Taiki, Mie 5192736, Japan 3.Nagoya Inst Technol, Grad Sch Engn, Dept Mat Sci & Engn, Showa Ku, Nagoya, Aichi 4668555, Japan 4.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
推荐引用方式 GB/T 7714	Kang, Yipu,Shimokawa, Yohei,Ishihara, Yasutaka,et al. Photoluminescence and cathodoluminescence properties of Li+ doped Gd1.88Eu0.12O3[J]. JOURNAL OF THE CERAMIC SOCIETY OF JAPAN,2015,123(1442):989-994.
APA	Kang, Yipu.,Shimokawa, Yohei.,Ishihara, Yasutaka.,Tsuji, Hitoshi.,Hashimoto, Shinobu.,...&Iwamoto, Yuji.(2015).Photoluminescence and cathodoluminescence properties of Li+ doped Gd1.88Eu0.12O3.JOURNAL OF THE CERAMIC SOCIETY OF JAPAN,123(1442),989-994.
MLA	Kang, Yipu,et al."Photoluminescence and cathodoluminescence properties of Li+ doped Gd1.88Eu0.12O3".JOURNAL OF THE CERAMIC SOCIETY OF JAPAN 123.1442(2015):989-994.