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Shape-controlled synthesis and influence of W doping and oxygen nonstoichiometry on the phase transition of VO2
Chen, Ru1,2; Miao, Lei1,3; Liu, Chengyan3; Zhou, Jianhua3; Cheng, Haoliang1; Asaka, Toru4; Iwamoto, Yuji4; Tanemura, Sakae1,3
2015-09-16
发表期刊SCIENTIFIC REPORTS
卷号5
摘要Monoclinic VO2(M) in nanostructure is a prototype material for interpreting correlation effects in solids with fully reversible phase transition and for the advanced applications to smart devices. Here, we report a facile one-step hydrothermal method for the controlled growth of single crystalline VO2(M/R) nanorods. Through tuning the hydrothermal temperature, duration of the hydrothermal time and W-doped level, single crystalline VO2(M/R) nanorods with controlled aspect ratio can be synthesized in large quantities, and the crucial parameter for the shape-controlled synthesis is the W-doped content. The dopant greatly promotes the preferential growth of (110) to form pure phase VO2(M/R) nanorods with high aspect ratio for the W-doped level = 2.0 at% sample. The shape-controlled process of VO2(M/R) nanorods upon W-doping are systematically studied. Moreover, the phase transition temperature (T-c) of VO2 depending on oxygen nonstoichiometry is investigated in detail.
文章类型Article
WOS标题词Science & Technology
DOI10.1038/srep14087
研究领域[WOS]Science & Technology - Other Topics
关键词[WOS]METAL-INSULATOR-TRANSITION ; CHEMICAL-VAPOR-DEPOSITION ; VANADIUM DIOXIDE ; SEMICONDUCTOR TRANSITION ; THERMOCHROMIC PROPERTIES ; HYDROTHERMAL SYNTHESIS ; TUNGSTEN ; FILMS ; NANOSTRUCTURES ; SPECTROSCOPY
收录类别SCI
语种英语
WOS类目Multidisciplinary Sciences
WOS记录号WOS:000361277200001
引用统计
被引频次:13[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/10866
专题中国科学院广州能源研究所
作者单位1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Guilin Univ Elect Technol, Sch Mat Sci & Engn, Guangxi Collaborat Innovat Ctr Struct & Property, Guangxi Key Lab Informat Mat, Guilin 541004, Peoples R China
4.Nagoya Inst Technol, Grad Sch Engn, Dept Frontier Mat, Showa Ku, Nagoya, Aichi 4668555, Japan
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Chen, Ru,Miao, Lei,Liu, Chengyan,et al. Shape-controlled synthesis and influence of W doping and oxygen nonstoichiometry on the phase transition of VO2[J]. SCIENTIFIC REPORTS,2015,5.
APA Chen, Ru.,Miao, Lei.,Liu, Chengyan.,Zhou, Jianhua.,Cheng, Haoliang.,...&Tanemura, Sakae.(2015).Shape-controlled synthesis and influence of W doping and oxygen nonstoichiometry on the phase transition of VO2.SCIENTIFIC REPORTS,5.
MLA Chen, Ru,et al."Shape-controlled synthesis and influence of W doping and oxygen nonstoichiometry on the phase transition of VO2".SCIENTIFIC REPORTS 5(2015).
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