Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
Shape-controlled synthesis and influence of W doping and oxygen nonstoichiometry on the phase transition of VO2 | |
Chen, Ru1,2; Miao, Lei1,3; Liu, Chengyan3; Zhou, Jianhua3; Cheng, Haoliang1; Asaka, Toru4; Iwamoto, Yuji4; Tanemura, Sakae1,3 | |
2015-09-16 | |
发表期刊 | SCIENTIFIC REPORTS |
卷号 | 5 |
摘要 | Monoclinic VO2(M) in nanostructure is a prototype material for interpreting correlation effects in solids with fully reversible phase transition and for the advanced applications to smart devices. Here, we report a facile one-step hydrothermal method for the controlled growth of single crystalline VO2(M/R) nanorods. Through tuning the hydrothermal temperature, duration of the hydrothermal time and W-doped level, single crystalline VO2(M/R) nanorods with controlled aspect ratio can be synthesized in large quantities, and the crucial parameter for the shape-controlled synthesis is the W-doped content. The dopant greatly promotes the preferential growth of (110) to form pure phase VO2(M/R) nanorods with high aspect ratio for the W-doped level = 2.0 at% sample. The shape-controlled process of VO2(M/R) nanorods upon W-doping are systematically studied. Moreover, the phase transition temperature (T-c) of VO2 depending on oxygen nonstoichiometry is investigated in detail. |
文章类型 | Article |
WOS标题词 | Science & Technology |
DOI | 10.1038/srep14087 |
研究领域[WOS] | Science & Technology - Other Topics |
关键词[WOS] | METAL-INSULATOR-TRANSITION ; CHEMICAL-VAPOR-DEPOSITION ; VANADIUM DIOXIDE ; SEMICONDUCTOR TRANSITION ; THERMOCHROMIC PROPERTIES ; HYDROTHERMAL SYNTHESIS ; TUNGSTEN ; FILMS ; NANOSTRUCTURES ; SPECTROSCOPY |
收录类别 | SCI |
语种 | 英语 |
WOS类目 | Multidisciplinary Sciences |
WOS记录号 | WOS:000361277200001 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.giec.ac.cn/handle/344007/10866 |
专题 | 中国科学院广州能源研究所 |
作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Guilin Univ Elect Technol, Sch Mat Sci & Engn, Guangxi Collaborat Innovat Ctr Struct & Property, Guangxi Key Lab Informat Mat, Guilin 541004, Peoples R China 4.Nagoya Inst Technol, Grad Sch Engn, Dept Frontier Mat, Showa Ku, Nagoya, Aichi 4668555, Japan |
第一作者单位 | 中国科学院广州能源研究所 |
推荐引用方式 GB/T 7714 | Chen, Ru,Miao, Lei,Liu, Chengyan,et al. Shape-controlled synthesis and influence of W doping and oxygen nonstoichiometry on the phase transition of VO2[J]. SCIENTIFIC REPORTS,2015,5. |
APA | Chen, Ru.,Miao, Lei.,Liu, Chengyan.,Zhou, Jianhua.,Cheng, Haoliang.,...&Tanemura, Sakae.(2015).Shape-controlled synthesis and influence of W doping and oxygen nonstoichiometry on the phase transition of VO2.SCIENTIFIC REPORTS,5. |
MLA | Chen, Ru,et al."Shape-controlled synthesis and influence of W doping and oxygen nonstoichiometry on the phase transition of VO2".SCIENTIFIC REPORTS 5(2015). |
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