A General Method Towards Efficient Synthesis and Fluorescence Tuning of Carbon Black-Derived Carbon Dots via Controlled Liquid Oxidization

doi:10.1071/CH15014

GIEC OpenIR > 中国科学院广州能源研究所

	A General Method Towards Efficient Synthesis and Fluorescence Tuning of Carbon Black-Derived Carbon Dots via Controlled Liquid Oxidization
	Yuan, Haoran1,2 ; Li, Denian 1,2; Liu, Yan 3,4; Xiong, Chuanxi 3,4,5
	2015
发表期刊	AUSTRALIAN JOURNAL OF CHEMISTRY
卷号	68 期号:9 页码:1446-1454
摘要	Efficient synthesis and controlled modification of carbon dots (CDs) with tuneable properties on the basis of facile technical routes are of great significance for user-defined applications as well as more insightful understanding of the unique fluorescence from carbon nanomaterials. In this work, we report an improved nitric acid oxidization method towards low-cost and rapid preparation of fluorescent CDs. This is achieved by using industrial carbon black specimens as the precursor and implementing a reduced pressure distillation for the purpose of eliminating excessive acids. Unexpectedly, the product exhibits an interesting dual luminescence behaviour with tuneable characteristics that differs from all previously reported CDs. The strongest emissions at fixed or varied excitations can be simultaneously tuned from blue to green or yellow by simply prolonging the time of acid oxidization. These emissions show distinct stabilities in acid and alkaline environments, thereby making the resultant CDs very promising candidates for pH probes. It is further revealed that this simple synthesis and fluorescence tuning strategy is also applicable to CDs from other carbon blacks.
文章类型	Article
WOS标题词	Science & Technology ; Physical Sciences
DOI	10.1071/CH15014
研究领域[WOS]	Chemistry
关键词[WOS]	GRAPHENE QUANTUM DOTS ; BAND-GAP ; NANOTUBES ; PHOTOLUMINESCENCE ; NANOPARTICLES ; FACILE ; SHEETS ; OXIDE ; SOOT
收录类别	SCI
语种	英语
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000360990400019
引用统计	被引频次：2[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/10859
专题	中国科学院广州能源研究所
作者单位	1.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 3.Wuhan Univ Technol, State Key Lab Adv Technol Mat Synth & Proc, Wuhan 430070, Peoples R China 4.Wuhan Univ Technol, Sch Mat Sci & Engn, Wuhan 430070, Peoples R China 5.Wuhan Text Univ, Sch Mat Sci & Engn, Wuhan 430070, Peoples R China
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Yuan, Haoran,Li, Denian,Liu, Yan,et al. A General Method Towards Efficient Synthesis and Fluorescence Tuning of Carbon Black-Derived Carbon Dots via Controlled Liquid Oxidization[J]. AUSTRALIAN JOURNAL OF CHEMISTRY,2015,68(9):1446-1454.
APA	Yuan, Haoran,Li, Denian,Liu, Yan,&Xiong, Chuanxi.(2015).A General Method Towards Efficient Synthesis and Fluorescence Tuning of Carbon Black-Derived Carbon Dots via Controlled Liquid Oxidization.AUSTRALIAN JOURNAL OF CHEMISTRY,68(9),1446-1454.
MLA	Yuan, Haoran,et al."A General Method Towards Efficient Synthesis and Fluorescence Tuning of Carbon Black-Derived Carbon Dots via Controlled Liquid Oxidization".AUSTRALIAN JOURNAL OF CHEMISTRY 68.9(2015):1446-1454.