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One-Pot Catalytic Conversion of Raw Lignocellulosic Biomass into Gasoline Alkanes and Chemicals over LiTaMoO6 and Ru/C in Aqueous Phosphoric Acid
Liu, Yong1,2; Chen, Lungang1; Wang, Tiejun1; Zhang, Qi1; Wang, Chenguang1; Yan, Jinyue3,4; Ma, Longlong1
2015-08-01
发表期刊ACS SUSTAINABLE CHEMISTRY & ENGINEERING
卷号3期号:8页码:1745-1755
摘要Lignocellulosic biomass is a renewable feedstock that has the potential to replace the diminishing fossil fuels. Herein, we reported the simultaneous conversion of cellulose, hemicellulose and lignin from raw biomass into gasoline alkanes (hexanes and pentanes) and monophenols and related hydrocarbons over layered LiTaMoO6 and Ru/C in aqueous phosphoric acid medium. Specifically, gasoline alkanes were directly yielded from the carbohydrate components, based on hemicellulose and cellulose, and the total yield could be up to 82.4%. Notably, the lignin fraction could also be transformed into monophenols, related alcohols and hydrocarbons by the one-pot reaction. It suggested that the hydrocracking of monophenol fraction could be performed in this catalytic system. The total yield of volatile products was 53% based on the lignin fraction. In this paper, the influences of phosphoric acid concentration, substrate ash and the amino acids derived from the biogenic impurities were investigated and different raw biomass substrates were tested. Furthermore, the catalysts could be reused for several runs to convert raw biomass without pretreatment.
文章类型Article
关键词Lignocellulosic Biomass Gasoline Alkanes Phenols Layered Compounds Catalytic Conversion
WOS标题词Science & Technology ; Physical Sciences ; Technology
DOI10.1021/acssuschemeng.5b00256
研究领域[WOS]Chemistry ; Engineering
关键词[WOS]ION-EXCHANGE-RESIN ; NONENZYMATIC SUGAR PRODUCTION ; LIGNIN DEPOLYMERIZATION ; LIQUID FUEL ; GLYCEROL HYDROGENOLYSIS ; SORBITOL TRANSFORMATION ; IR-REOX/SIO2 CATALYST ; TRANSPORTATION FUELS ; BIMETALLIC CATALYSTS ; GAMMA-VALEROLACTONE
收录类别SCI
语种英语
WOS类目Chemistry, Multidisciplinary ; Engineering, Chemical
WOS记录号WOS:000359098400010
引用统计
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/10841
专题中国科学院广州能源研究所
作者单位1.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Royal Inst Technol, Sch Chem Engn & Technol, SE-10044 Stockholm, Sweden
4.Malardalen Univ, Sch Sustainable Dev Soc & Technol, SE-72123 Vasteras, Sweden
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Liu, Yong,Chen, Lungang,Wang, Tiejun,et al. One-Pot Catalytic Conversion of Raw Lignocellulosic Biomass into Gasoline Alkanes and Chemicals over LiTaMoO6 and Ru/C in Aqueous Phosphoric Acid[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2015,3(8):1745-1755.
APA Liu, Yong.,Chen, Lungang.,Wang, Tiejun.,Zhang, Qi.,Wang, Chenguang.,...&Ma, Longlong.(2015).One-Pot Catalytic Conversion of Raw Lignocellulosic Biomass into Gasoline Alkanes and Chemicals over LiTaMoO6 and Ru/C in Aqueous Phosphoric Acid.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,3(8),1745-1755.
MLA Liu, Yong,et al."One-Pot Catalytic Conversion of Raw Lignocellulosic Biomass into Gasoline Alkanes and Chemicals over LiTaMoO6 and Ru/C in Aqueous Phosphoric Acid".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 3.8(2015):1745-1755.
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