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One-step hydrothermal synthesis of V1-xWxO2 (M/R) nanorods with superior doping efficiency and thermochromic properties
Chen, Ru1,2; Miao, Lei1; Cheng, Haoliang1; Nishibori, Eiji3,5; Liu, Chengyan1; Asaka, Toru4; Iwamoto, Yuji4; Takata, Masaki5; Tanemura, Sakae1
2015
Source PublicationJOURNAL OF MATERIALS CHEMISTRY A
Volume3Issue:7Pages:3726-3738
AbstractPure phase V1-xWxO2(M/R) nanorods with superb metal-insulator transition properties were obtained in tungsten (W)-doped level ranges from 0.5 to 2.0 at% using a one-step hydrothermal treatment without additional annealing steps. The assured level of W doping greatly promotes the grain growth of pure phase vanadium oxide (VO2)(M/R) and simultaneously the phase transition temperature (T-c) is depressed as much as 103 degrees C per at% W for the V1-xWxO2 nanorods when x = 1.0-2.0 at%. After mixing the pure phase VO2(M) (W-doped 0.5 at%, phase transition at 47 degrees C) nanorods with acrylic resin, the integrated visible transmission of the VO2 composite coating on glass is up to 60.6% and the integrated solar modulation efficiency is up to 10.3%. These results mean that the superior thermochromic property will greatly favor the practical application of VO(2)(-)based smart windows.
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
DOI10.1039/c4ta05559d
WOS Subject ExtendedChemistry ; Energy & Fuels ; Materials Science
WOS KeywordMETAL-INSULATOR-TRANSITION ; RECTANGULAR CROSS-SECTIONS ; CHEMICAL-VAPOR-DEPOSITION ; VANADIUM DIOXIDE ; PHASE-TRANSITION ; IRREVERSIBLE TRANSFORMATION ; MAGNETIC-PROPERTIES ; CRYSTAL-STRUCTURES ; VO2 NANOPARTICLES ; DOPED VO2
Indexed BySCI
Language英语
WOS SubjectChemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary
WOS IDWOS:000349447200061
Citation statistics
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/10801
Collection中国科学院广州能源研究所
Affiliation1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Univ Tsukuba, Ctr Integrated Res Fundamental Sci & Engn CiRfSE, Tsukuba Res Ctr Interdisciplinary Mat Sci TIMS, Div Phys,Fac Pure & Appl Sci, Tsukuba, Ibaraki 3058576, Japan
4.Nagoya Inst Technol, Grad Sch Engn, Dept Frontier Mat, Showa Ku, Nagoya, Aichi 4668555, Japan
5.RIKEN, RIKEN SPring Ctr 8, Struct Mat Sci Lab, Koto, Hyogo 6795148, Japan
First Author AffilicationGuangZhou Institute of Energy Conversion,Chinese Academy of Sciences
Recommended Citation
GB/T 7714
Chen, Ru,Miao, Lei,Cheng, Haoliang,et al. One-step hydrothermal synthesis of V1-xWxO2 (M/R) nanorods with superior doping efficiency and thermochromic properties[J]. JOURNAL OF MATERIALS CHEMISTRY A,2015,3(7):3726-3738.
APA Chen, Ru.,Miao, Lei.,Cheng, Haoliang.,Nishibori, Eiji.,Liu, Chengyan.,...&Tanemura, Sakae.(2015).One-step hydrothermal synthesis of V1-xWxO2 (M/R) nanorods with superior doping efficiency and thermochromic properties.JOURNAL OF MATERIALS CHEMISTRY A,3(7),3726-3738.
MLA Chen, Ru,et al."One-step hydrothermal synthesis of V1-xWxO2 (M/R) nanorods with superior doping efficiency and thermochromic properties".JOURNAL OF MATERIALS CHEMISTRY A 3.7(2015):3726-3738.
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