Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| Organosilicon functionalized glycerol carbonates as electrolytes for lithium-ion batteries | |
Wang, Jinglun1 ; Yong, Tianqiao1,2; Yang, Jianwen3; Ouyang, Chuying4; Zhang, Lingzhi1
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| 2015 | |
| Source Publication | RSC ADVANCES
 |
| Volume | 5Issue:23Pages:17660-17666 |
| Abstract | Two triethoxyl-/trimethoxyl-silyl functionalized glycerol carbonates and one disiloxanyl functionalized glycerol carbonate were synthesized through a cycloaddition reaction of carbon dioxide with allyl glycidyl ether followed by a hydrosilylation with the corresponding hydrosilanes. Their chemical structures were fully characterized by H-1 and C-13 nuclear magnetic resonance (NMR) spectroscopy and their basic physicochemical properties including dielectric constant, viscosity, ionic conductivity, apparent lithium transference number and electrochemical window, were systematically measured. Trimethoxysilyl functionalized glycerol carbonate as electrolyte solvent with LiPF6 (0.6 M) and lithium oxalyldifluoroborate (0.4 M) binary salts exhibited good cycling stability over 2.7-4.4 V in high-voltage-LiCoO2/graphite full cells. Disiloxane functionalized glycerol carbonate acted as an efficient electrolyte additive to improve the wetting property on the separator in Li/LiCoO2 cells. |
| Subtype | Article |
| WOS Headings | Science & Technology ; Physical Sciences |
| DOI | 10.1039/c4ra15854g |
| WOS Subject Extended | Chemistry |
| WOS Keyword | VINYL ETHYLENE CARBONATE ; CELLS ; ADDITIVES ; SOLVENTS ; SURFACE ; LIQUID ; PERFORMANCE ; ELECTRODES ; STABILITY ; SILANE |
| Indexed By | SCI |
| Language | 英语 |
| WOS Subject | Chemistry, Multidisciplinary |
| WOS ID | WOS:000349557400038 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/10799 |
| Collection | 中国科学院广州能源研究所 |
| Affiliation | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China 3.Guilin Univ Technol, Coll Chem & Bioengn, Guilin 541004, Guangxi, Peoples R China 4.Jiangxi Normal Univ, Dept Phys, Nanchang 330022, Peoples R China |
| First Author Affilication | GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences |
| Recommended Citation GB/T 7714 | Wang, Jinglun,Yong, Tianqiao,Yang, Jianwen,et al. Organosilicon functionalized glycerol carbonates as electrolytes for lithium-ion batteries[J]. RSC ADVANCES,2015,5(23):17660-17666. |
| APA | Wang, Jinglun,Yong, Tianqiao,Yang, Jianwen,Ouyang, Chuying,&Zhang, Lingzhi.(2015).Organosilicon functionalized glycerol carbonates as electrolytes for lithium-ion batteries.RSC ADVANCES,5(23),17660-17666. |
| MLA | Wang, Jinglun,et al."Organosilicon functionalized glycerol carbonates as electrolytes for lithium-ion batteries".RSC ADVANCES 5.23(2015):17660-17666. |
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