Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| One-Step Approach to 2,5-Diformylfuran from Fructose by Using a Bifunctional and Recyclable Acidic Polyoxometalate Catalyst | |
Liu, Ruliang1,3; Chen, Jinzhu1 ; Chen, Limin2; Guo, Yuanyuan1; Zhong, Jiawei1,3
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| 2014-10-01 | |
| Source Publication | CHEMPLUSCHEM
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| Volume | 79Issue:10Pages:1448-1454 |
| Abstract | A series of acidic cesium salts of molybdovanadophosphoric heteropolyacids (CsMVP-HPAs) are developed as bifunctional and recyclable catalysts for a one-step approach to 2,5-diformylfuran (DFF) from fructose with molecular oxygen as the oxidant under environmentally benign conditions. The CsMVP-HPAs afford the direct synthesis of DFF from fructose through acidic site (H)-promoted fructose dehydration and metallic site (V)-catalyzed successive aerobic oxidation of 5-hydroxymethylfurfural (HMF). The catalytic performances of CsMVP-HPA toward fructose dehydration and HMF oxidation are related to its acid density and V content, respectively. Moreover, the increase in the V content of CsMVP-HPA results in its decreased acid density, which suggests its converse catalytic performance toward fructose dehydration and HMF oxidation. An optimum balance between the dehydration and oxidation functions of CsMVP-HPAs reveals that a ratio of acid density to molar concentration of V between 1.64 and 3.34 achieves a maximum yield of 60% for DFF from fructose with Cs3HPMo11VO40 as a catalyst under atmospheric pressure of oxygen. Moreover, Cs3HPMo11VO40 behaves as a heterogeneous catalyst and can be easily reused at least for four times. This research highlights an efficient bifunctional catalyst for transforming renewables into fine chemicals in tandem reactions of dehydration and oxidation. |
| Subtype | Article |
| Keyword | Biomass Domino Reactions Furans Heterogeneous Catalysis Polyoxometalates |
| WOS Headings | Science & Technology ; Physical Sciences |
| DOI | 10.1002/cplu.201402147 |
| WOS Subject Extended | Chemistry |
| WOS Keyword | EFFICIENT AEROBIC OXIDATION ; SELECTIVE OXIDATION ; ONE-POT ; 2,5-FURANDICARBOXYLIC ACID ; SURFACE-STRUCTURES ; BIOMASS ; FUELS ; CONVERSION ; OXIDE ; DERIVATIVES |
| Indexed By | SCI |
| Language | 英语 |
| WOS Subject | Chemistry, Multidisciplinary |
| WOS ID | WOS:000342797000006 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/10784 |
| Collection | 中国科学院广州能源研究所 |
| Affiliation | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 2.S China Univ Technol, Coll Environm & Energy, Guangzhou 510006, Guangdong, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| First Author Affilication | GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences |
| Recommended Citation GB/T 7714 | Liu, Ruliang,Chen, Jinzhu,Chen, Limin,et al. One-Step Approach to 2,5-Diformylfuran from Fructose by Using a Bifunctional and Recyclable Acidic Polyoxometalate Catalyst[J]. CHEMPLUSCHEM,2014,79(10):1448-1454. |
| APA | Liu, Ruliang,Chen, Jinzhu,Chen, Limin,Guo, Yuanyuan,&Zhong, Jiawei.(2014).One-Step Approach to 2,5-Diformylfuran from Fructose by Using a Bifunctional and Recyclable Acidic Polyoxometalate Catalyst.CHEMPLUSCHEM,79(10),1448-1454. |
| MLA | Liu, Ruliang,et al."One-Step Approach to 2,5-Diformylfuran from Fructose by Using a Bifunctional and Recyclable Acidic Polyoxometalate Catalyst".CHEMPLUSCHEM 79.10(2014):1448-1454. |
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