Catalytic effects of NaOH and Na2CO3 additives on alkali lignin pyrolysis and gasification

doi:10.1016/j.apenergy.2012.01.042

GIEC OpenIR > 中国科学院广州能源研究所

	Catalytic effects of NaOH and Na2CO3 additives on alkali lignin pyrolysis and gasification
	Guo, Da-liang 1; Wu, Shu-bin 1; Liu, Bei 1; Yin, Xiu-li 2; Yang, Qing 2
	2012-07-01
发表期刊	APPLIED ENERGY
卷号	95 页码:22-30
摘要	The interest in utilization of alkali lignin in black liquor by pyrolysis and gasification is increasing due to the wish to produce bio-fuel and bio-chemical. Besides alkali lignin, the sodium salts are also the basic component of black liquor; they exist in two main forms: as phenolic sodium (-CONa) and carboxylate sodium (-COONa) groups forming a part of alkali lignin or as dissolved salts (NaOH and Na2CO3). In this paper, the influences of these dissolved salts on the pyrolysis and gasification characteristics of alkali lignin were discussed. Five lignin samples, including pure acid precipitated lignin, 10% and 60% NaOH-loaded lignin, 10% and 60% Na2CO3-loaded lignin, and black liquor solids were selected as the testing samples. Following experimental research on the evolution patterns of volatile products were carried Out on a thermogravimetric analyzer coupled with Fourier transform infrared spectrometry. The experimental data indicated that the pyrolysis and gasification reaction of alkali lignin could be catalyzed by NaOH and Na2CO3. In the pyrolysis stage, the maximum mass loss rate decreased with increasing amount of NaOH and Na2CO3 additives, while in the gasification stage it increased. In the gasification stage, the temperature of the maximum mass loss rate shifted to lower value with increasing amount of NaOH and Na2CO3 additives, but did not significantly change in the pyrolysis stage. FTIR analysis showed that the influences of NaOH and Na2CO3 additives on the pyrolysis and gasification products mainly varied in amounts but not in species. FTIR results also suggested that the release time of the volatile was affected by increasing NaOH and Na2CO3 additives amount. Moreover, NaOH and Na2CO3 markedly improved the evolution of CO in the gasification stage. (C) 2012 Elsevier Ltd. All rights reserved.
文章类型	Article
关键词	Lignin Black Liquor Pyrolysis And Gasification Naoh And Na2co3 Tg-ftir
WOS标题词	Science & Technology ; Technology
DOI	10.1016/j.apenergy.2012.01.042
研究领域[WOS]	Energy & Fuels ; Engineering
关键词[WOS]	TG-FTIR ANALYSIS ; BLACK LIQUOR GASIFICATION ; ENZYMATIC/MILD ACIDOLYSIS LIGNIN ; VICTORIAN BROWN-COAL ; WHEAT-STRAW ; KINETICS ; NITROGEN ; BIOMASS ; PULP ; VOLATILIZATION
收录类别	SCI
语种	英语
WOS类目	Energy & Fuels ; Engineering, Chemical
WOS记录号	WOS:000303365900003
引用统计	被引频次：118[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/10577
专题	中国科学院广州能源研究所
作者单位	1.S China Univ Technol, State Key Lab Pulp & Paper Engn, Guangzhou 510640, Guangdong, Peoples R China 2.Chinese Acad Sci, Renewable Energy & Gas Hydrate Key Lab CAS, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China
推荐引用方式 GB/T 7714	Guo, Da-liang,Wu, Shu-bin,Liu, Bei,et al. Catalytic effects of NaOH and Na2CO3 additives on alkali lignin pyrolysis and gasification[J]. APPLIED ENERGY,2012,95:22-30.
APA	Guo, Da-liang,Wu, Shu-bin,Liu, Bei,Yin, Xiu-li,&Yang, Qing.(2012).Catalytic effects of NaOH and Na2CO3 additives on alkali lignin pyrolysis and gasification.APPLIED ENERGY,95,22-30.
MLA	Guo, Da-liang,et al."Catalytic effects of NaOH and Na2CO3 additives on alkali lignin pyrolysis and gasification".APPLIED ENERGY 95(2012):22-30.