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Hydrodeoxygenation of vegetable oils to liquid alkane fuels over Ni/HZSM-5 catalysts: Methyl hexadecanoate as the model compound
Shi, Na; Liu, Qi-ying; Jiang, Ting; Wang, Tie-jun; Ma, Long-long; Zhang, Qi; Zhang, Xing-hua
2012-04-05
发表期刊CATALYSIS COMMUNICATIONS
卷号20页码:80-84
摘要Ni/HZSM-5 catalysts with different Ni loadings were prepared by impregnation method, and their catalytic performance was evaluated in the hydrodeoxygenation (HDO) upgrading of the model reactant methyl hexadecanoate (MHD) to liquid alkane fuels. The physicochemical properties of the catalysts were characterized by XRD, SEM, NH3-TPD, and BET. Ni loadings were obviously influenced by the acidity, and thus significantly affected their catalytic performance. Over 7 wt.% Ni/HZSM-5 catalyst, MHD conversion of more than 90% and total liquid C-5-C-16 hydrocarbon selectivity of 83% were obtained under the optimum reaction condition, possibly due to the synergistic effect of metal Ni and acid HZSM-5. (C) 2012 Elsevier B.V. All rights reserved.
文章类型Article
关键词Hydrodeoxygenation Methyl Hexadecanoate Biofuels Ni/hzsm-5 Catalyst
WOS标题词Science & Technology ; Physical Sciences
DOI10.1016/j.catcom.2012.01.007
研究领域[WOS]Chemistry
关键词[WOS]SULFIDED NIMO/GAMMA-AL2O3 ; ALIPHATIC ESTERS ; HYDROISOMERIZATION ; PERFORMANCE ; DIESEL ; ACID
收录类别SCI
语种英语
WOS类目Chemistry, Physical
WOS记录号WOS:000302110700017
引用统计
被引频次:50[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/10562
专题中国科学院广州能源研究所
作者单位Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy & Gas Hydrate, Guangzhou, Guangdong, Peoples R China
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GB/T 7714
Shi, Na,Liu, Qi-ying,Jiang, Ting,et al. Hydrodeoxygenation of vegetable oils to liquid alkane fuels over Ni/HZSM-5 catalysts: Methyl hexadecanoate as the model compound[J]. CATALYSIS COMMUNICATIONS,2012,20:80-84.
APA Shi, Na.,Liu, Qi-ying.,Jiang, Ting.,Wang, Tie-jun.,Ma, Long-long.,...&Zhang, Xing-hua.(2012).Hydrodeoxygenation of vegetable oils to liquid alkane fuels over Ni/HZSM-5 catalysts: Methyl hexadecanoate as the model compound.CATALYSIS COMMUNICATIONS,20,80-84.
MLA Shi, Na,et al."Hydrodeoxygenation of vegetable oils to liquid alkane fuels over Ni/HZSM-5 catalysts: Methyl hexadecanoate as the model compound".CATALYSIS COMMUNICATIONS 20(2012):80-84.
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