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Preparation of jet fuel range hydrocarbons by catalytic transformation of bio-oil derived from fast pyrolysis of straw stalk
Wang, Jicong1; Bi, Peiyan1; Zhang, Yajing1; Xue, He1; Jiang, Peiwen1; Wu, Xiaoping1; Liu, Junxu1; Wang, Tiejun2; Li, Quanxin1
2015-06-15
Source PublicationENERGY
Volume86Pages:488-499
AbstractThe growing demand of commercial jet fuels, in combination with the strict environmental legislations, has led to immense interest in developing aviation biofuels. This work demonstrated that the bio-oil derived from fast pyrolysis of straw stalk was able to be converted into the jet and diesel fuel range hydrocarbons by a designed transformation route. This transformation included three reaction steps: (i) the catalytic cracking of bio-oil into low-carbon aromatics and light olefins, (ii) the synthesis of C8-C15 aromatic hydrocarbons by the alkylation of low-carbon aromatics with light olefins, and (iii) the production of C8-C15 cyclic alkanes by the hydrogenation of C8-C15 aromatics. It was also demonstrated that the production of the desired C8-C15 aromatics with a high selectivity of 88.4% was achieved by the low temperature alkylation reactions of the bio-oil-derived aromatics using the ionic liquid of [bmim]Cl-2AlCl(3) (1-butyl-3-methylimidazolium chloroaluminate). The synthetic biofuels basically met the main technical specifications of jet fuels based on the combustion heat, viscosity, freeze point and other characteristics of fuels. (C) 2015 Elsevier Ltd. All rights reserved.
SubtypeArticle
KeywordBio-oil Jet Fuels C-8-c-15 Hydrocarbons Alkylation
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
DOI10.1016/j.energy.2015.04.053
WOS Subject ExtendedThermodynamics ; Energy & Fuels
WOS KeywordIONIC LIQUIDS ; ORGANIC-COMPOUNDS ; CONVERSION ; ACIDITY ; HYDROCRACKING ; FEEDSTOCKS ; BIODIESEL ; DIESEL ; BIOREFINERIES ; HEMICELLULOSE
Indexed BySCI
Language英语
WOS SubjectThermodynamics ; Energy & Fuels
WOS IDWOS:000356986300046
Citation statistics
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/10513
Collection中国科学院广州能源研究所
Affiliation1.Univ Sci & Technol China, Dept Chem Phys, Anhui Key Lab Biomass Clean Energy, Hefei 230026, Peoples R China
2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy & Gas Hydrate, Guangzhou 510640, Guangdong, Peoples R China
Recommended Citation
GB/T 7714
Wang, Jicong,Bi, Peiyan,Zhang, Yajing,et al. Preparation of jet fuel range hydrocarbons by catalytic transformation of bio-oil derived from fast pyrolysis of straw stalk[J]. ENERGY,2015,86:488-499.
APA Wang, Jicong.,Bi, Peiyan.,Zhang, Yajing.,Xue, He.,Jiang, Peiwen.,...&Li, Quanxin.(2015).Preparation of jet fuel range hydrocarbons by catalytic transformation of bio-oil derived from fast pyrolysis of straw stalk.ENERGY,86,488-499.
MLA Wang, Jicong,et al."Preparation of jet fuel range hydrocarbons by catalytic transformation of bio-oil derived from fast pyrolysis of straw stalk".ENERGY 86(2015):488-499.
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