The first observation of titanate nanotubes by spherical aberration corrected high-resolution transmission electron microscopy

doi:10.1016/j.spmi.2008.12.017

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	The first observation of titanate nanotubes by spherical aberration corrected high-resolution transmission electron microscopy
	Miao, L.1,2 ; Tanemura, S.1,2; Jiang, T.3; Tanemura, M.3; Yoshida, K.1,5; Tanaka, N.4; Xu, G.2
	2009-07-01
发表期刊	SUPERLATTICES AND MICROSTRUCTURES
卷号	46 期号:1-2 页码:357-364
摘要	Multi-wall titanate nanotubes (MW-TNNTs) with high aspect ratio, large surface area and good uniformity were produced by alkaline hydrothermal treatment of grounded TiO(2) aerogels and further by applying freeze-drying. Not only the crystal phase and diameter, but also morphology of the starting materials impact on the aspect ratio and transformation efficiency of the obtained nanotubes. Other parameters, such as pH value during neutralization process and drying method for the final products, are important to control length and dispersion of MW-TNNTs. By spherical aberration corrected high-resolution transmission-electron-microscopy (Cs-corrected HRTEM) with lateral space resolution of 0.14 nm at 200 W accelerating voltage and electron energy loss spectrum (EELS), the detailed structural analysis of MW-TNNTs reveals that (1) diameters of inner and outer tubes are about 4-7 nm and 10 nm, respectively, (2) numbers of layers are different from part to part along the longitudinal tube axis, (3) the walls of the tubes have interlayer spacing of 0.70-0.80 nm and the lateral fringes which are vertical to the walls have spacing of 0.32 nm, (4) each layer of MW-TNNT is the nanosheet composed by the arrayed TiO(6) octahedrons, and respective octahedron being slightly strained, and (5) no chirality of MW-TNNT tubular structure is observed. (C) 2009 Published by Elsevier Ltd
文章类型	Article
关键词	Hydrothermal Method Titanium Dioxide And Titanate Nanotubes Spherical Aberration Corrected Tem Chirality Eels
WOS标题词	Science & Technology ; Physical Sciences
DOI	10.1016/j.spmi.2008.12.017
研究领域[WOS]	Physics
关键词[WOS]	CRYSTALLINE TIO2 NANOTUBES ; FABRICATION ; TITANIUM ; WATER ; HYDROGEN ; FILMS
收录类别	SCI ; ISTP
语种	英语
WOS类目	Physics, Condensed Matter
WOS记录号	WOS:000267444900061
引用统计	被引频次：9[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/10304
专题	中国科学院广州能源研究所
作者单位	1.Japan Fine Ceram Ctr, Mat R&D Lab, Atsuta Ku, Nagoya, Aichi 4568587, Japan 2.Chinese Acad Sci, Key Lab Renewable Energy & Gas Hydrate, Gangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 3.Nagoya Inst Technol, Dept Environm Technol, Grad Sch Engn, Showa Ku, Nagoya, Aichi 4668555, Japan 4.Nagoya Univ, EcoTopia Sci Inst, Chikusa Ku, Nagoya, Aichi 4648603, Japan 5.Nagoya Univ, Dept Crystalline Mat Sci, Chikusa Ku, Nagoya, Aichi 4648603, Japan
推荐引用方式 GB/T 7714	Miao, L.,Tanemura, S.,Jiang, T.,et al. The first observation of titanate nanotubes by spherical aberration corrected high-resolution transmission electron microscopy[J]. SUPERLATTICES AND MICROSTRUCTURES,2009,46(1-2):357-364.
APA	Miao, L..,Tanemura, S..,Jiang, T..,Tanemura, M..,Yoshida, K..,...&Xu, G..(2009).The first observation of titanate nanotubes by spherical aberration corrected high-resolution transmission electron microscopy.SUPERLATTICES AND MICROSTRUCTURES,46(1-2),357-364.
MLA	Miao, L.,et al."The first observation of titanate nanotubes by spherical aberration corrected high-resolution transmission electron microscopy".SUPERLATTICES AND MICROSTRUCTURES 46.1-2(2009):357-364.