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The role of CeO(2)-ZrO(2) as support in the ZnO-ZnCr(2)O(4) catalysts for autothermal reforming of methanol
Liu, Na1,2; Yuan, Zhongshan1; Wang, Congwei3; Wang, Shudong1; Zhang, Chunxi1; Wang, Shujuan1
2008-06-01
Source PublicationFUEL PROCESSING TECHNOLOGY
Volume89Issue:6Pages:574-581
AbstractAutothermal reforming of methanol for hydrogen production was investigated over ZnO-ZnCr(2)O(4) supported on a series of metal oxides (Al(2)O(3), CeO(2), ZrO(2) and CeO(2)-ZrO(2))CeO(2)-ZrO(2) mixed oxides with Ce /Zr molar ratio of 4/1 was found to be the optimal support which showed significant effect on the catalytic activity and selectivity. The ZnO-ZnCr(2)O(4)/CeO(2)-ZrO(2) and ZnO-ZnCr(2)O(4) catalysts were characterized by XRD, TEM, H(2)-TPR and XPS. The results show that CeO(2)-ZrO(2) mixed oxides have significant effect on the catalytic performance and the supported catalyst shows more uniform temperature distribution in the catalyst bed which was mainly due to its reasonable redox properties. (C) 2007 Published by Elsevier B.V.
SubtypeArticle
KeywordHydrogen Production Methanol Autothermal Reforming Zno Ceo(2)-zro(2)
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
DOI10.1016/j.fuproc.2007.11.029
WOS Subject ExtendedChemistry ; Energy & Fuels ; Engineering
WOS KeywordALCOHOL SYNTHESIS CATALYSTS ; FUEL-CELL APPLICATIONS ; HYDROGEN-PRODUCTION ; SURFACE CHARACTERIZATION ; CUO/CEO2 CATALYSTS ; REDOX BEHAVIOR ; ZN/CR SPINEL ; MIXED OXIDES ; PD/ZNO ; PERFORMANCE
Indexed BySCI
Language英语
WOS SubjectChemistry, Applied ; Energy & Fuels ; Engineering, Chemical
WOS IDWOS:000256820600002
Citation statistics
Cited Times:22[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/10288
Collection中国科学院广州能源研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
3.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China
Recommended Citation
GB/T 7714
Liu, Na,Yuan, Zhongshan,Wang, Congwei,et al. The role of CeO(2)-ZrO(2) as support in the ZnO-ZnCr(2)O(4) catalysts for autothermal reforming of methanol[J]. FUEL PROCESSING TECHNOLOGY,2008,89(6):574-581.
APA Liu, Na,Yuan, Zhongshan,Wang, Congwei,Wang, Shudong,Zhang, Chunxi,&Wang, Shujuan.(2008).The role of CeO(2)-ZrO(2) as support in the ZnO-ZnCr(2)O(4) catalysts for autothermal reforming of methanol.FUEL PROCESSING TECHNOLOGY,89(6),574-581.
MLA Liu, Na,et al."The role of CeO(2)-ZrO(2) as support in the ZnO-ZnCr(2)O(4) catalysts for autothermal reforming of methanol".FUEL PROCESSING TECHNOLOGY 89.6(2008):574-581.
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