Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
The role of CeO(2)-ZrO(2) as support in the ZnO-ZnCr(2)O(4) catalysts for autothermal reforming of methanol | |
Liu, Na1,2; Yuan, Zhongshan1; Wang, Congwei3; Wang, Shudong1; Zhang, Chunxi1; Wang, Shujuan1 | |
2008-06-01 | |
发表期刊 | FUEL PROCESSING TECHNOLOGY |
卷号 | 89期号:6页码:574-581 |
摘要 | Autothermal reforming of methanol for hydrogen production was investigated over ZnO-ZnCr(2)O(4) supported on a series of metal oxides (Al(2)O(3), CeO(2), ZrO(2) and CeO(2)-ZrO(2))CeO(2)-ZrO(2) mixed oxides with Ce /Zr molar ratio of 4/1 was found to be the optimal support which showed significant effect on the catalytic activity and selectivity. The ZnO-ZnCr(2)O(4)/CeO(2)-ZrO(2) and ZnO-ZnCr(2)O(4) catalysts were characterized by XRD, TEM, H(2)-TPR and XPS. The results show that CeO(2)-ZrO(2) mixed oxides have significant effect on the catalytic performance and the supported catalyst shows more uniform temperature distribution in the catalyst bed which was mainly due to its reasonable redox properties. (C) 2007 Published by Elsevier B.V. |
文章类型 | Article |
关键词 | Hydrogen Production Methanol Autothermal Reforming Zno Ceo(2)-zro(2) |
WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
DOI | 10.1016/j.fuproc.2007.11.029 |
研究领域[WOS] | Chemistry ; Energy & Fuels ; Engineering |
关键词[WOS] | ALCOHOL SYNTHESIS CATALYSTS ; FUEL-CELL APPLICATIONS ; HYDROGEN-PRODUCTION ; SURFACE CHARACTERIZATION ; CUO/CEO2 CATALYSTS ; REDOX BEHAVIOR ; ZN/CR SPINEL ; MIXED OXIDES ; PD/ZNO ; PERFORMANCE |
收录类别 | SCI |
语种 | 英语 |
WOS类目 | Chemistry, Applied ; Energy & Fuels ; Engineering, Chemical |
WOS记录号 | WOS:000256820600002 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.giec.ac.cn/handle/344007/10288 |
专题 | 中国科学院广州能源研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China |
推荐引用方式 GB/T 7714 | Liu, Na,Yuan, Zhongshan,Wang, Congwei,et al. The role of CeO(2)-ZrO(2) as support in the ZnO-ZnCr(2)O(4) catalysts for autothermal reforming of methanol[J]. FUEL PROCESSING TECHNOLOGY,2008,89(6):574-581. |
APA | Liu, Na,Yuan, Zhongshan,Wang, Congwei,Wang, Shudong,Zhang, Chunxi,&Wang, Shujuan.(2008).The role of CeO(2)-ZrO(2) as support in the ZnO-ZnCr(2)O(4) catalysts for autothermal reforming of methanol.FUEL PROCESSING TECHNOLOGY,89(6),574-581. |
MLA | Liu, Na,et al."The role of CeO(2)-ZrO(2) as support in the ZnO-ZnCr(2)O(4) catalysts for autothermal reforming of methanol".FUEL PROCESSING TECHNOLOGY 89.6(2008):574-581. |
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