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Prediction of equilibrium hydrate formation conditions for gas mixtures using the statistical associating fluid theory equation of state
Li Xiao-Sen; Wu Hui-Jie; Feng Zi-Peng; Tang Liang-Guang; Fan Shuan-Shi
2007-01-14
Source PublicationACTA CHIMICA SINICA
Volume65Issue:1Pages:59-66
AbstractThe statistical associating fluid theory (SAFT) equation of state in conjunction with the statistical model of van der Waals and Platteeuw was employed to predict the formation equilibrium conditions of binary gas mixtures containing methane, ethane, propane, ethylene, propylene, H(2)S CO(2), N(2) and H(2) in the presence of aqueous solutions. The SAFT equation was used to describe the vapor and liquid phases. In calculation, the SAFT took into account hard sphere repulsion, hard chain formation, dispersion and association interactions. The van der Waals and Platteeuw model was applied to calculate the hydrate phase. The predictions were found to be in quite good agreement with the experimental data.
SubtypeArticle
KeywordGas Hydrate The Statistical Associating Fluid Theory Equation Of State Equilibrium Formation Condition
WOS HeadingsScience & Technology ; Physical Sciences
WOS Subject ExtendedChemistry
WOS KeywordTHERMODYNAMIC PERTURBATION-THEORY ; VAPOR-LIQUID-EQUILIBRIUM ; TREBBLE-BISHNOI EQUATION ; DISSOCIATION PRESSURES ; PHASE-EQUILIBRIA ; CARBON-DIOXIDE ; METHANOL ; SYSTEMS ; SAFT ; REPRESENTATION
Indexed BySCI
Language英语
WOS SubjectChemistry, Multidisciplinary
WOS IDWOS:000243606300011
Citation statistics
Cited Times:6[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/10271
Collection中国科学院广州能源研究所
Recommended Citation
GB/T 7714
Li Xiao-Sen,Wu Hui-Jie,Feng Zi-Peng,et al. Prediction of equilibrium hydrate formation conditions for gas mixtures using the statistical associating fluid theory equation of state[J]. ACTA CHIMICA SINICA,2007,65(1):59-66.
APA Li Xiao-Sen,Wu Hui-Jie,Feng Zi-Peng,Tang Liang-Guang,&Fan Shuan-Shi.(2007).Prediction of equilibrium hydrate formation conditions for gas mixtures using the statistical associating fluid theory equation of state.ACTA CHIMICA SINICA,65(1),59-66.
MLA Li Xiao-Sen,et al."Prediction of equilibrium hydrate formation conditions for gas mixtures using the statistical associating fluid theory equation of state".ACTA CHIMICA SINICA 65.1(2007):59-66.
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