Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
Hydrogen from acetic acid as the model compound of biomass fast-pyralysis oil over Ni catalyst supported on ceria-zirconia | |
Zheng, Xiao-xiao; Yan, Chang-feng; Hu, Rong-rong; Li, Juan; Hai, Hang; Luo, Wei-min; Guo, Chang-qing; Li, Wen-bo; Zhou, Zhou-yu | |
2012-09-01 | |
发表期刊 | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY |
卷号 | 37期号:17页码:12987-12993 |
摘要 | Hydrogen production from catalytic steam reforming of model compound acetic acid of bio-oil was investigated under atmospheric pressure in a bench-scale fixed-bed reactor and a series of Ni catalysts supported on ceria-zirconia were prepared via co-precipitation with varying contents of Ni and Ce loading. Simultaneously, effects of reaction temperature, and molar ratio of steam to carbon fed, liquid hourly space velocity (LHSV) were also explored. The results indicated that the 12Ni/7.5Ce-Zr-O catalyst was superior to other catalysts with different Ni and Ce loading. At T = 650 degrees C, S/C = 3, LHSV = 2.8 h(-1), the reaction over Ni catalyst supported on ceria-zirconia turns out that the highest activity and the maximum hydrogen selectivity of 83.4% and the minimum methane selectivity of 0.39% are attained. Besides, Ni catalyst supported on ceria-zirconia shows good stability during 25 h continuous reaction without any deactivation. Copyright (C) 2012, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved. |
文章类型 | Article |
关键词 | Bio-oil Model Compound Acetic Acid Hydrogen Ni Catalyst Supported On ceria-zircoNia |
WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
DOI | 10.1016/j.ijhydene.2012.05.067 |
研究领域[WOS] | Chemistry ; Electrochemistry ; Energy & Fuels |
关键词[WOS] | BIO-OIL ; NICKEL-CATALYSTS ; AQUEOUS FRACTION ; FAST PYROLYSIS ; GASIFICATION ; OXIDES |
收录类别 | SCI |
语种 | 英语 |
WOS类目 | Chemistry, Physical ; Electrochemistry ; Energy & Fuels |
WOS记录号 | WOS:000309024700110 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.giec.ac.cn/handle/344007/10167 |
专题 | 中国科学院广州能源研究所 |
作者单位 | Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China |
推荐引用方式 GB/T 7714 | Zheng, Xiao-xiao,Yan, Chang-feng,Hu, Rong-rong,et al. Hydrogen from acetic acid as the model compound of biomass fast-pyralysis oil over Ni catalyst supported on ceria-zirconia[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2012,37(17):12987-12993. |
APA | Zheng, Xiao-xiao.,Yan, Chang-feng.,Hu, Rong-rong.,Li, Juan.,Hai, Hang.,...&Zhou, Zhou-yu.(2012).Hydrogen from acetic acid as the model compound of biomass fast-pyralysis oil over Ni catalyst supported on ceria-zirconia.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,37(17),12987-12993. |
MLA | Zheng, Xiao-xiao,et al."Hydrogen from acetic acid as the model compound of biomass fast-pyralysis oil over Ni catalyst supported on ceria-zirconia".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 37.17(2012):12987-12993. |
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