Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
One-pot aqueous phase catalytic conversion of sorbitol to gasoline over nickel catalyst | |
Weng, Yujing1,2; Qiu, Songbai1; Xu, Ying1; Ding, Mingyue1; Chen, Lungang1; Zhang, Qi1; Ma, Longlong1; Wang, Tiejun1 | |
2015-04-01 | |
发表期刊 | ENERGY CONVERSION AND MANAGEMENT |
卷号 | 94页码:95-102 |
摘要 | The carbon chain extension and hydrodeoxygenation steps play critical roles in the high-energy-density hydrocarbons production. In this paper, a systematic study had been carried out to investigate one-pot aqueous phase catalytic conversion of sorbitol to gasoline (STG) over bifunctional Ni-based catalysts. Characterization technologies of N-2 physisorption, X-ray diffraction (XRD), Scanning electron microscopy (SEM), transmission electron microscopy (TEM) and NH3 temperature-programmed desorption (NH3-TPD) were used to study the textural properties, phase compositions, acid behavior and morphologies of the catalysts. The catalytic performances were tested in a fixed bed reactor. It was found that the physically mixed Ni/HZSM-5 and Ni/silica-gel (mesoporous SG) catalyst realized the carbon chain extension and exhibited excellent performances on hydrodeoxygenation (HDO) reaction (46.9% of gasoline (C5-C12) yield and 45.5% of C7-C12 hydrocarbons in the gasoline products). Especially, the temperature of STG (553-593 K) was lower obviously than that of the traditional methanol to gasoline (MTG) process (623-773 K). It provided a novel transformation of sorbitol to long-chain alkanes by one-pot process over the bifunctional catalyst (Ni@HZSM-5/SG), wherein hydrodeoxygenation, ketonization and aldol condensation steps were integrated. (C) 2015 Elsevier Ltd. All rights reserved. |
文章类型 | Article |
关键词 | Sugar Alcohol Aqueous Phase Catalytic Conversion SorbiTol To Gasoline |
WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
DOI | 10.1016/j.enconman.2015.01.054 |
研究领域[WOS] | Thermodynamics ; Energy & Fuels ; Mechanics ; Physics |
关键词[WOS] | SOLVOLYSED LIGNOCELLULOSIC BIOMASS ; C COUPLING REACTIONS ; FUEL-GRADE COMPOUNDS ; OXYGENATED HYDROCARBONS ; NI/HZSM-5 CATALYSTS ; LIQUID ALKANES ; PENTANE PRODUCTION ; HYDRODEOXYGENATION ; NI ; TRANSFORMATION |
收录类别 | SCI |
语种 | 英语 |
WOS类目 | Thermodynamics ; Energy & Fuels ; Mechanics ; Physics, Nuclear |
WOS记录号 | WOS:000351811000009 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.giec.ac.cn/handle/344007/9106 |
专题 | 中国科学院广州能源研究所 |
作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
第一作者单位 | 中国科学院广州能源研究所 |
推荐引用方式 GB/T 7714 | Weng, Yujing,Qiu, Songbai,Xu, Ying,et al. One-pot aqueous phase catalytic conversion of sorbitol to gasoline over nickel catalyst[J]. ENERGY CONVERSION AND MANAGEMENT,2015,94:95-102. |
APA | Weng, Yujing.,Qiu, Songbai.,Xu, Ying.,Ding, Mingyue.,Chen, Lungang.,...&Wang, Tiejun.(2015).One-pot aqueous phase catalytic conversion of sorbitol to gasoline over nickel catalyst.ENERGY CONVERSION AND MANAGEMENT,94,95-102. |
MLA | Weng, Yujing,et al."One-pot aqueous phase catalytic conversion of sorbitol to gasoline over nickel catalyst".ENERGY CONVERSION AND MANAGEMENT 94(2015):95-102. |
条目包含的文件 | 条目无相关文件。 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论