TPAOH Template Removal from High-Silica ZSM-5 by Low-Temperature Hydrocracking

doi:10.3866/PKU.WHXB201503021

GIEC OpenIR > 中国科学院广州能源研究所

	TPAOH Template Removal from High-Silica ZSM-5 by Low-Temperature Hydrocracking
	Zhao Shu-Heng 1,2; Lang Lin1 ; Yin Xiu-Li1 ; Yang Wen-Shen 1; Wu Chuang-Zhi1
	2015-04-01
发表期刊	ACTA PHYSICO-CHIMICA SINICA
卷号	31 期号:4 页码:793-799
摘要	Zeolite membranes, especially the MFI-type zeolite membranes, have attracted significant attention for decades because of their special properties. While organic templates such as tetrapropylammonium hydroxide (TPAOH) have typically been used for the synthesis of ZSM-5 zeolite and zeolite membranes, the templates remain trapped in the as-synthesized zeolite crystals. A common method for removing organic templates and generating porous frameworks is calcination; however, during this process, the channel structure may be affected. In particular, for ZSM-5 membranes, membrane defects may be produced and the separation efficiency therefore may decrease to some extent. In this study, the low-temperature hydrocracking of TPAOH in ZSM-5 zeolite crystals was studied under H-2/N-2, while N-2 adsorption, thermogravimetric (TG) analysis, Fourier transform infrared (FTIR) spectroscopy, temperature-programmed desorption of ammonia (NH3-TPD), and Raman spectroscopy were used to characterize zeolite samples. The results show that the organic template in the pores of ZSM-5 can be effectively removed below 350 degrees C by low-temperature hydrocracking. Characterization analyses by BET specific surface area, TG, FTIR, and Raman spectroscopy demonstrated that a reducing atmosphere containing H-2 was more conducive to template removal at low temperature than atmospheres of air or N-2. The degree of template removal increased with temperature increasing. The BET surface area of the crystal after hydrocracking at 280 degrees C reached 252 m(2).g(-1), although a small amount of organic residue remained. Furthermore, after hydrocracking at 350 degrees C, the BET surface area reached 399 m(2).g(-1), and only trace amount of inorganic carbon residue remained. In addition, the introduction of hydrogen at low temperatures could prevent coke deposits on acid sites and thus ZSM-5 zeolite crystals had greater numbers of acidic sites after low-temperature hydrocracking.
文章类型	Article
关键词	Zsm-5 Zeolite Template Removal Low-temperature Hydrocracking High Si/al Ratio Tetrapropylammonium Hydroxide
WOS标题词	Science & Technology ; Physical Sciences
DOI	10.3866/PKU.WHXB201503021
研究领域[WOS]	Chemistry
关键词[WOS]	MFI ZEOLITE FILMS ; ORGANIC TEMPLATE ; SEPARATION PERFORMANCE ; UV/OZONE TREATMENT ; SECONDARY GROWTH ; THIN-FILMS ; MEMBRANES ; DEACTIVATION ; IMPROVEMENT ; OXIDATION
收录类别	SCI
语种	英语
WOS类目	Chemistry, Physical
WOS记录号	WOS:000354153800024
引用统计	被引频次：3[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/9086
专题	中国科学院广州能源研究所生物质能源生物质热化学转化实验室
作者单位	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Zhao Shu-Heng,Lang Lin,Yin Xiu-Li,et al. TPAOH Template Removal from High-Silica ZSM-5 by Low-Temperature Hydrocracking[J]. ACTA PHYSICO-CHIMICA SINICA,2015,31(4):793-799.
APA	Zhao Shu-Heng,Lang Lin,Yin Xiu-Li,Yang Wen-Shen,&Wu Chuang-Zhi.(2015).TPAOH Template Removal from High-Silica ZSM-5 by Low-Temperature Hydrocracking.ACTA PHYSICO-CHIMICA SINICA,31(4),793-799.
MLA	Zhao Shu-Heng,et al."TPAOH Template Removal from High-Silica ZSM-5 by Low-Temperature Hydrocracking".ACTA PHYSICO-CHIMICA SINICA 31.4(2015):793-799.