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Biodiesel from different oil using fixed-bed and plug-flow reactors
Lu, Pengmei; Yuan, Zhenhong; Li, Lianhua; Wang, Zhongming; Luo, Wen
2010
发表期刊RENEWABLE ENERGY
ISSN0960-1481
卷号35期号:1页码:283-287
产权排序[Lu, Pengmei; Yuan, Zhenhong; Li, Lianhua; Wang, Zhongming; Luo, Wen] Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy & Gas Hydrate, Guangzhou 510640, Guangdong, Peoples R China
通讯作者lvpm@ms.giec.ac.cn
摘要In this study, a pilot scale of 100 t/year biodiesel production system, mainly consisting of a fixed-bed and a down-stream plug-flow reactors, was setup to test different feedstock oils, especially a kind of high-acidified oil, trap grease, for their feasibility as biodiesel feedstock in China. The tested oils include three kinds of typical oil from Guangdong Province, China: rapeseed oil, Chinese wood oil, and trap grease. At the same time the optimum residence time for a plug-now reactor to perform transesterification reaction was investigated in this study. At the temperature of 65 degrees C, methanol/oil molar ratio of 6:1 and KOH load of 1.2 wt% of oil, the optimum residence time was found to be 19 min. A type of ion-exchange resin was used to fill in the fixed-bed reactor and used as the esterification catalyst for pretreating on the high-acidified oil. For the fresh catalyst, the acid value of trap grease could be reduced from 114 mg KOH/g to about 2 mg KOH/g after 13 h at temperature 75 degrees C, catalyst load of 15 wt% of oil, methanol addition of 20 wt% of oil. The lifetime test for the catalyst indicated that its life is over 30 days. The quality of biodiesel derived from three feedstock oils is compared with newly published China BD100 standard of GB/T20828-2007. A comparison of the results reveals that the biodiesel generated through this system could satisfactorily meet China BD100 standard. It indicates that the designed process in this system has a good adaptability for different kinds of oil. (C) 2009 Elsevier Ltd. All rights reserved.
文章类型Article
其他摘要In this study, a pilot scale of 100 t/year biodiesel production system, mainly consisting of a fixed-bed and a down-stream plug-flow reactors, was setup to test different feedstock oils, especially a kind of high-acidified oil, trap grease, for their feasibility as biodiesel feedstock in China. The tested oils include three kinds of typical oil from Guangdong Province, China: rapeseed oil, Chinese wood oil, and trap grease. At the same time the optimum residence time for a plug-now reactor to perform transesterification reaction was investigated in this study. At the temperature of 65 degrees C, methanol/oil molar ratio of 6:1 and KOH load of 1.2 wt% of oil, the optimum residence time was found to be 19 min. A type of ion-exchange resin was used to fill in the fixed-bed reactor and used as the esterification catalyst for pretreating on the high-acidified oil. For the fresh catalyst, the acid value of trap grease could be reduced from 114 mg KOH/g to about 2 mg KOH/g after 13 h at temperature 75 degrees C, catalyst load of 15 wt% of oil, methanol addition of 20 wt% of oil. The lifetime test for the catalyst indicated that its life is over 30 days. The quality of biodiesel derived from three feedstock oils is compared with newly published China BD100 standard of GB/T20828-2007. A comparison of the results reveals that the biodiesel generated through this system could satisfactorily meet China BD100 standard. It indicates that the designed process in this system has a good adaptability for different kinds of oil. (C) 2009 Elsevier Ltd. All rights reserved.
关键词Biodiesel Plug-flow Fixed-bed Rapeseed Oil Chinese Wood Oil Trap Grease
学科领域Energy & Fuels
WOS标题词Science & Technology ; Technology
DOI10.1016/j.renene.2009.07.011
研究领域[WOS]Energy & Fuels
URL查看原文
关键词[WOS]WASTE COOKING OIL ; FREE FATTY-ACIDS ; SEED OIL
收录类别SCI
语种英语
项目资助者High Technology RD Program [2007AA05Z412]; Guangdong Province Key Technology [200649851301]
WOS类目Energy & Fuels
WOS记录号WOS:000279550600036
引用统计
被引频次:44[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/8522
专题中国科学院广州能源研究所
生物质能源生化转化实验室
作者单位Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy & Gas Hydrate, Guangzhou 510640, Guangdong, Peoples R China
推荐引用方式
GB/T 7714
Lu, Pengmei,Yuan, Zhenhong,Li, Lianhua,et al. Biodiesel from different oil using fixed-bed and plug-flow reactors[J]. RENEWABLE ENERGY,2010,35(1):283-287.
APA Lu, Pengmei,Yuan, Zhenhong,Li, Lianhua,Wang, Zhongming,&Luo, Wen.(2010).Biodiesel from different oil using fixed-bed and plug-flow reactors.RENEWABLE ENERGY,35(1),283-287.
MLA Lu, Pengmei,et al."Biodiesel from different oil using fixed-bed and plug-flow reactors".RENEWABLE ENERGY 35.1(2010):283-287.
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