Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| The nanometer magnetic solid base catalyst for production of biodiesel | |
Liu, Chang1,2; Lv, Pengmei1 ; Yuan, Zhenhong1; Yan, Fang1; Luo, Wen1
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| 2010-07-01 | |
| 发表期刊 | RENEWABLE ENERGY
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| ISSN | 0960-1481 |
| 卷号 | 35期号:7页码:1531-1536 |
| 产权排序 | [Liu, Chang; Lv, Pengmei; Yuan, Zhenhong; Yan, Fang; Luo, Wen] Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy & Gas Hydrate, Guangzhou 510640, Guangdong, Peoples R China; [Liu, Chang] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 通讯作者 | lvpm@ms.giec.ac.cn |
| 摘要 | Nanometer magnetic solid base catalysts were prepared by loading CaO on Fe(3)O(4) with Na(2)CO(3) and NaOH as precipitator, respectively. The optimum conditions for preparation of this catalyst were investigated. The influence of the proportion of Ca(2+) to Fe(3)O(4) on the catalytic performance has been studied. The catalyst with highest catalytic activity has been obtained when the proportion of Ca(2+) to Fe(3)O(4) is 7:1: the catalytic activity of the catalyst calcined from Ca(OH)(2) to Fe(3)O(4) is better than that calcined from CaCO(3) to Fe(3)O(4); under the conditions of methanol/oil molar ratio of 15:1, catalyst dosage of 2 wt% and temperature of 70 degrees C, the biodiesel yield reaches to 95% in 80 min, even to 99% finally. The catalytic activity and recovery rate of the nanometer magnetic solid base catalysts are much better than those of CaO. Calcination temperature was determined by differential thermogravimetric analysis. Ca(2)Fe(2)O(5), a kind of new metal multiple oxide, was found in the catalyst through X-ray diffraction. At the end, these catalysts were characterized by scanning electronic microscope (SEM), transmission electron microscopy (TEM), and vibrating sample magnetometer (VSM). (C) 2009 Elsevier Ltd. All rights reserved. |
| 文章类型 | Article |
| 其他摘要 | Nanometer magnetic solid base catalysts were prepared by loading CaO on Fe(3)O(4) with Na(2)CO(3) and NaOH as precipitator, respectively. The optimum conditions for preparation of this catalyst were investigated. The influence of the proportion of Ca(2+) to Fe(3)O(4) on the catalytic performance has been studied. The catalyst with highest catalytic activity has been obtained when the proportion of Ca(2+) to Fe(3)O(4) is 7:1: the catalytic activity of the catalyst calcined from Ca(OH)(2) to Fe(3)O(4) is better than that calcined from CaCO(3) to Fe(3)O(4); under the conditions of methanol/oil molar ratio of 15:1, catalyst dosage of 2 wt% and temperature of 70 degrees C, the biodiesel yield reaches to 95% in 80 min, even to 99% finally. The catalytic activity and recovery rate of the nanometer magnetic solid base catalysts are much better than those of CaO. Calcination temperature was determined by differential thermogravimetric analysis. Ca(2)Fe(2)O(5), a kind of new metal multiple oxide, was found in the catalyst through X-ray diffraction. At the end, these catalysts were characterized by scanning electronic microscope (SEM), transmission electron microscopy (TEM), and vibrating sample magnetometer (VSM). (C) 2009 Elsevier Ltd. All rights reserved. |
| 关键词 | Biodiesel Transesterification Nanometer Magnetic Solid Base New Crystalloid |
| 学科领域 | Energy & Fuels |
| WOS标题词 | Science & Technology ; Technology |
| DOI | 10.1016/j.renene.2009.10.009 |
| 研究领域[WOS] | Energy & Fuels |
| URL | 查看原文 |
| 关键词[WOS] | SOYBEAN OIL ; VEGETABLE-OIL ; EARTH METALS ; TRANSESTERIFICATION ; ALUMINA ; OXIDE ; FAT |
| 收录类别 | SCI |
| 语种 | 英语 |
| 项目资助者 | High Technology RD Program [2007AA05Z412]; 2006 Guangdong Province Key Technology [200649851301] |
| WOS类目 | Energy & Fuels |
| WOS记录号 | WOS:000276082900026 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.giec.ac.cn/handle/344007/8495 |
| 专题 | 中国科学院广州能源研究所 生物质能源生化转化实验室 |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy & Gas Hydrate, Guangzhou 510640, Guangdong, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Chang,Lv, Pengmei,Yuan, Zhenhong,et al. The nanometer magnetic solid base catalyst for production of biodiesel[J]. RENEWABLE ENERGY,2010,35(7):1531-1536. |
| APA | Liu, Chang,Lv, Pengmei,Yuan, Zhenhong,Yan, Fang,&Luo, Wen.(2010).The nanometer magnetic solid base catalyst for production of biodiesel.RENEWABLE ENERGY,35(7),1531-1536. |
| MLA | Liu, Chang,et al."The nanometer magnetic solid base catalyst for production of biodiesel".RENEWABLE ENERGY 35.7(2010):1531-1536. |
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