Electroplating sludge-derived magnetic copper-containing catalysts for selective hydrogenation of bio-based furfural

doi:10.1007/s13399-022-02970-8

GIEC OpenIR

	Electroplating sludge-derived magnetic copper-containing catalysts for selective hydrogenation of bio-based furfural
	Xiao, Yaoxin 1,2; Zhang, Jun 2,3,4,5; Zhu, Lingjun 6; Shan, Rui 2,3,4,5; Yuan, Haoran1,2,3,4,5 ; Chen, Yong1,2,3,4,5
	2022-07-04
发表期刊	BIOMASS CONVERSION AND BIOREFINERY
ISSN	2190-6815
页码	12
通讯作者	Yuan, Haoran(yuanhr@ms.giec.ac.cn)
摘要	A series of inexpensive electroplating sludge-derived magnetic copper-containing catalysts were developed for the selective hydrogenation of biomass-based furfural (FFR) into furfuryl alcohol (FA) and 2-methylfuran (MF). The specific structural characteristics of as-prepared magnetic copper-containing samples were clearly identified through various techniques, including XRD, XPS, N-2 adsorption-desorption, NH3-TPD, SEM and so on. The characterizations revealed that the hydrogen pre-activated magnetic catalysts supplied metallic Cu species, medium acidity and porosity for the catalytic upgrading of FFR in hydrogen atmosphere. As for FFR-to-FA as well as FFR-to-MF transformations, the magnetic copper-containing catalyst with calcination temperature of 800 degrees C exhibited excellent performance towards the formation of FA and MF, wherein desirable FA yield of 98.5 mol% and MF yield of 71.3 mol% were achieved at reaction temperatures of 160 degrees C and 240 degrees C, respectively. The reuse experiments indicated that the recycled catalysts still maintained excellent activity and stability even after four-time recycling. The present study thus highlights a new approach for the resource utilization of electroplating sludge, which also supplies low-cost and efficient catalytic materials for the selective upgrading of various biomass-derived platform molecules.
关键词	Electroplating sludge Magnetic catalysts Furfural Selective hydrogenation
DOI	10.1007/s13399-022-02970-8
关键词[WOS]	CONVERSION ; ALCOHOL ; CYCLOPENTANONE ; 2-METHYLFURAN ; ACID
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[51976222] ; Key Special Project for Introduced Talents Team of Southern Marine Science and Engineering Guangdong Laboratory (Guangzhou)[GML2019ZD0101] ; State Key Laboratory of Clean Energy Utilization[ZJUCEU2020023]
WOS研究方向	Energy & Fuels ; Engineering
项目资助者	National Natural Science Foundation of China ; Key Special Project for Introduced Talents Team of Southern Marine Science and Engineering Guangdong Laboratory (Guangzhou) ; State Key Laboratory of Clean Energy Utilization
WOS类目	Energy & Fuels ; Engineering, Chemical
WOS记录号	WOS:000820121200002
出版者	SPRINGER HEIDELBERG
引用统计	被引频次：2[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/36938
专题	中国科学院广州能源研究所
通讯作者	Yuan, Haoran
作者单位	1.South China Agr Univ, Inst Biomass Engn, Guangzhou 510642, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 3.Southern Marine Sci & Engn Guangdong Lab Guangzho, Guangzhou 511458, Peoples R China 4.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China 5.CAS Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 6.Zhejiang Univ, State Key Lab Clean Energy Utilizat, Hangzhou 310027, Peoples R China
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Xiao, Yaoxin,Zhang, Jun,Zhu, Lingjun,et al. Electroplating sludge-derived magnetic copper-containing catalysts for selective hydrogenation of bio-based furfural[J]. BIOMASS CONVERSION AND BIOREFINERY,2022:12.
APA	Xiao, Yaoxin,Zhang, Jun,Zhu, Lingjun,Shan, Rui,Yuan, Haoran,&Chen, Yong.(2022).Electroplating sludge-derived magnetic copper-containing catalysts for selective hydrogenation of bio-based furfural.BIOMASS CONVERSION AND BIOREFINERY,12.
MLA	Xiao, Yaoxin,et al."Electroplating sludge-derived magnetic copper-containing catalysts for selective hydrogenation of bio-based furfural".BIOMASS CONVERSION AND BIOREFINERY (2022):12.