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Towards directional pyrolysis of xylan: Understanding the roles of alkali/alkaline earth metals and pyrolysis temperature
Zeng, Kuo1; Wang, Biao1,2,3,4; Xia, Shengpeng2,3,4,5; Cui, Chaoxian2,3,4,5; Wang, Chenyang2,3,4,5; Zheng, Anqing2,3,4; Zhao, Kun2,3,4; Zhao, Zengli2,3,4; Li, Haibin2,3,4; Isobaev, M. D.6
2022-09-01
发表期刊ENERGY
ISSN0360-5442
卷号254页码:10
通讯作者Zheng, Anqing(zhengaq@ms.giec.ac.cn) ; Zhao, Kun(zhaokun@ms.giec.ac.cn)
摘要To identify the roles of alkali/alkaline earth metals (AAEM) and reaction temperature during pyrolysis of hemicellulose, the effects of AAEM doping on the pyrolysis behaviors, kinetics, and product yields of xylan at different pyrolysis temperatures were assessed. The results demonstrated that the yields of anhydrosugars from pyrolysis of xylan were dependent on the AAEM cations and their doping concentrations. Demineralization achieved the directional conversion of xylan into xylosan at 300 degrees C. The doping of even 0.05 mmol/g AAEM significantly suppressed their formation. The yields of xylosan from pyrolysis of xylan doped with different AAEM cations decreased in the following order: Mg2+
关键词Biomass pyrolysis Hemicellulose pyrolysis Alkali and alkaline earth metals Pretreatment Anhydrosugars
DOI10.1016/j.energy.2022.124245
关键词[WOS]CATALYTIC FAST PYROLYSIS ; LIGNOCELLULOSIC BIOMASS ; HEMICELLULOSE ; CELLULOSE ; MECHANISM ; GLUCOSE ; LIGNIN ; SALTS ; MODEL
收录类别SCI
语种英语
资助项目National Key R&D Program of China[2017YFE0124200] ; National Natural Science Founda-tion of China[51876208] ; National Natural Science Founda-tion of China[51776209] ; Major International (Regional) Joint Research Project of the National Science Founda-tion of China[51661145011] ; Youth Innovation Promotion Association, CAS[2018383] ; Pearl River S&T Nova Program of Guangzhou[201806010061]
WOS研究方向Thermodynamics ; Energy & Fuels
项目资助者National Key R&D Program of China ; National Natural Science Founda-tion of China ; Major International (Regional) Joint Research Project of the National Science Founda-tion of China ; Youth Innovation Promotion Association, CAS ; Pearl River S&T Nova Program of Guangzhou
WOS类目Thermodynamics ; Energy & Fuels
WOS记录号WOS:000808005500013
出版者PERGAMON-ELSEVIER SCIENCE LTD
引用统计
被引频次:3[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/36806
专题中国科学院广州能源研究所
通讯作者Zheng, Anqing; Zhao, Kun
作者单位1.Huazhong Univ Sci & Technol, State Key Lab Coal Combust, Wuhan 430074, Hubei, Peoples R China
2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China
3.CAS Key Lab Renewable Energy, Guangzhou 510640, Peoples R China
4.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China
5.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
6.Acad Sci Tajikistan, Nikitin Inst Chem, Dushanbe 734063, Tajikistan
推荐引用方式
GB/T 7714
Zeng, Kuo,Wang, Biao,Xia, Shengpeng,et al. Towards directional pyrolysis of xylan: Understanding the roles of alkali/alkaline earth metals and pyrolysis temperature[J]. ENERGY,2022,254:10.
APA Zeng, Kuo.,Wang, Biao.,Xia, Shengpeng.,Cui, Chaoxian.,Wang, Chenyang.,...&Isobaev, M. D..(2022).Towards directional pyrolysis of xylan: Understanding the roles of alkali/alkaline earth metals and pyrolysis temperature.ENERGY,254,10.
MLA Zeng, Kuo,et al."Towards directional pyrolysis of xylan: Understanding the roles of alkali/alkaline earth metals and pyrolysis temperature".ENERGY 254(2022):10.
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