Hierarchical WMoC nano array with optimal crystal facet as a non-noble metal cathode for proton exchange membrane water electrolyser

doi:10.1016/j.jpowsour.2022.231557

GIEC OpenIR

	Hierarchical WMoC nano array with optimal crystal facet as a non-noble metal cathode for proton exchange membrane water electrolyser
	Shen, Lisha 1; Shi, Yan 1; Ogundipe, Taiwo Oladapo 1,2; Huang, Kai 1,2; Cao, Shuo 3; Lu, Zhuoxin 1; Wang, Zhida 1; Tan, Hongyi 1; Yan, Changfeng1,2
	2022-08-01
发表期刊	JOURNAL OF POWER SOURCES
ISSN	0378-7753
卷号	538 页码:8
通讯作者	Shi, Yan(shiyan@ms.giec.ac.cn) ; Yan, Changfeng(yancf@ms.giec.ac.cn)
摘要	Highly efficient non-noble metal hydrogen evolution reaction (HER) catalysts are of particular importance for cost-effective proton exchange membrane water electrolyser (PEMWE). Here, hierarchical WMoC nano arrays (NAs) with superhydrophilic surface and optimal crystal facet is synthesized. Mo plays a crucial role in preferred growth of active crystal facet and the formation of NA. Thanks to the optimal crystal facet and unique structure, WMoC NA exhibits an enhanced HER activity and stability under high current density. PEMWE single cell based on WMoC cathode shows an outstanding performance, which obtains a current density of 1 A cm-2 at voltage of 1.888 V with N117 at 80 degrees C, making it one of the best PEMWEs using non-noble metal cathode. The single cell also shows a stable operation under 1A cm-2 at 80 degrees C over 700 h, demonstrating WMoC cathode's great potential for application use.
关键词	Water electrolysis Proton exchange membrane Non -noble metal Hydrogen evolution Tungsten carbide
DOI	10.1016/j.jpowsour.2022.231557
关键词[WOS]	TOTAL-ENERGY CALCULATIONS ; CARBIDE NANOPARTICLES ; MOLYBDENUM CARBIDE ; CATALYST ; ELECTROCATALYSTS ; CARBON ; PERFORMANCE ; TRANSITION ; FABRICATION ; SULFIDE
收录类别	SCI
语种	英语
资助项目	Guangzhou Sci-ence and Technology Project[202102020961] ; Guangzhou Sci-ence and Technology Project[202002030349] ; Guangzhou Sci-ence and Technology Project[202103040002] ; Natural Science Foundation of Hebei Province[B2019205240] ; STS Project of Chinese Academy of Sciences[KFJ-STS-QYZD-2021-02-003] ; Basic and applied basic research project of Guangdong Province[2021B1515120072]
WOS研究方向	Chemistry ; Electrochemistry ; Energy & Fuels ; Materials Science
项目资助者	Guangzhou Sci-ence and Technology Project ; Natural Science Foundation of Hebei Province ; STS Project of Chinese Academy of Sciences ; Basic and applied basic research project of Guangdong Province
WOS类目	Chemistry, Physical ; Electrochemistry ; Energy & Fuels ; Materials Science, Multidisciplinary
WOS记录号	WOS:000798957800002
出版者	ELSEVIER
引用统计	被引频次：8[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/36687
专题	中国科学院广州能源研究所
通讯作者	Shi, Yan; Yan, Changfeng
作者单位	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510650, Peoples R China 2.Univ Chinese Acad Sci, Hefei 230026, Peoples R China 3.Chinese Acad Sci, Inst Met Res, Shenyang 110000, Peoples R China
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Shen, Lisha,Shi, Yan,Ogundipe, Taiwo Oladapo,et al. Hierarchical WMoC nano array with optimal crystal facet as a non-noble metal cathode for proton exchange membrane water electrolyser[J]. JOURNAL OF POWER SOURCES,2022,538:8.
APA	Shen, Lisha.,Shi, Yan.,Ogundipe, Taiwo Oladapo.,Huang, Kai.,Cao, Shuo.,...&Yan, Changfeng.(2022).Hierarchical WMoC nano array with optimal crystal facet as a non-noble metal cathode for proton exchange membrane water electrolyser.JOURNAL OF POWER SOURCES,538,8.
MLA	Shen, Lisha,et al."Hierarchical WMoC nano array with optimal crystal facet as a non-noble metal cathode for proton exchange membrane water electrolyser".JOURNAL OF POWER SOURCES 538(2022):8.