Selective Hydrogenolysis of 5-Hydroxymethylfurfural to 2-Hexanol over Au/ZrO2 Catalysts

doi:10.1002/cssc.202200092

GIEC OpenIR

	Selective Hydrogenolysis of 5-Hydroxymethylfurfural to 2-Hexanol over Au/ZrO2 Catalysts
	Hu, Xiaohong 1,2,3; Li, Zhijian 1,2,4; Wang, Haiyong 1,2; Xin, Haosheng 1,2,3; Li, Song 1,2; Wang, Chenguang 1,2,4; Ma, Longlong1,2,4 ; Liu, Qiying1,2,4
	2022-05-13
发表期刊	CHEMSUSCHEM
ISSN	1864-5631
页码	13
通讯作者	Ma, Longlong(mall@ms.giec.ac.cn) ; Liu, Qiying(liuqy@ms.giec.ac.cn)
摘要	2-Hexanol (2-HOL) is a versatile biomass-derived platform molecule for synthesis of liquid transportation fuels, lubricants, or detergents. Herein, a one-step preparation of 2-HOL using 5-hydroxymethylfurfural (HMF) as a substrate was reported for the first time. Several Au-based catalysts supported on different metal oxides were prepared to explore the relationship between carrier and catalytic activity. The results showed that the highest 2-HOL yield of 65.8 % was obtained at complete HMF conversion over the 5 %Au/ZrO2 catalyst. The 5 %Au/ZrO2 catalyst exhibited excellent durability after five consecutive recycling runs, while confirming its remarkable ring-opening hydrogenolysis on other biomass-derived furanics, furfural, with a total yield of 1-pentanol and 2-pentanol of 67.4 %. The distinguished ring-opening hydrogenolysis performance of the Au/ZrO2 catalyst originated from a synergistic effect between the interfacial Au-O-Zr oxygen vacancies-induced Lewis acidic sites (activating C-OH/C=O bonds) and metallic Au (activating H-2). This work provides a possibility for producing 2-HOL from HMF with high yield, expanding the sustainable application of lignocellulosic biomass.
关键词	2-hexanol 5-hydroxymethylfurfural biomass conversion heterogeneous catalysis hydrogenolysis
DOI	10.1002/cssc.202200092
关键词[WOS]	GAS SHIFT REACTION ; FORMIC-ACID ; 2,5-FURANDICARBOXYLIC ACID ; DIKETONE DERIVATIVES ; CO OXIDATION ; CONVERSION ; GOLD ; AU ; BIOMASS ; 2,5-DIMETHYLFURAN
收录类别	SCI
语种	英语
资助项目	National Key Research and Development Program of China[2018YFB1501402] ; National Natural Science Foundation of China[51976220] ; R & D Plan of Key Fields in Guangdong Province[2020B1111570001]
WOS研究方向	Chemistry ; Science & Technology - Other Topics
项目资助者	National Key Research and Development Program of China ; National Natural Science Foundation of China ; R & D Plan of Key Fields in Guangdong Province
WOS类目	Chemistry, Multidisciplinary ; Green & Sustainable Science & Technology
WOS记录号	WOS:000795962900001
出版者	WILEY-V C H VERLAG GMBH
引用统计	被引频次：7[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/36547
专题	中国科学院广州能源研究所
通讯作者	Ma, Longlong; Liu, Qiying
作者单位	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 2.Guangdong Prov Key Lab New & Renewable Energy Res, CAS Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 4.Univ Sci & Technol China, Hefei 230026, Peoples R China
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Hu, Xiaohong,Li, Zhijian,Wang, Haiyong,et al. Selective Hydrogenolysis of 5-Hydroxymethylfurfural to 2-Hexanol over Au/ZrO2 Catalysts[J]. CHEMSUSCHEM,2022:13.
APA	Hu, Xiaohong.,Li, Zhijian.,Wang, Haiyong.,Xin, Haosheng.,Li, Song.,...&Liu, Qiying.(2022).Selective Hydrogenolysis of 5-Hydroxymethylfurfural to 2-Hexanol over Au/ZrO2 Catalysts.CHEMSUSCHEM,13.
MLA	Hu, Xiaohong,et al."Selective Hydrogenolysis of 5-Hydroxymethylfurfural to 2-Hexanol over Au/ZrO2 Catalysts".CHEMSUSCHEM (2022):13.