Biomass-derived 2-methyltetrahydrofuran platform: a focus on precious and non-precious metal-based catalysts for the biorefinery

doi:10.1039/d2gc00759b

GIEC OpenIR

	Biomass-derived 2-methyltetrahydrofuran platform: a focus on precious and non-precious metal-based catalysts for the biorefinery
	Alorku, Kingdom 1,2,3,4; Shen, Chen 1,2,3,4; Li, Yuhang 1,2,3,4; Xu, Ying1,2,3,4 ; Wang, Chenguang 1,2,3,4; Liu, Qiying1,2,3,4
	2022-06-06
发表期刊	GREEN CHEMISTRY
ISSN	1463-9262
卷号	24 期号:11 页码:4201-4236
通讯作者	Liu, Qiying(liuqy@ms.giec.ac.cn)
摘要	Biomass conversion to platform chemicals, value-added chemicals, or fuels is important because it provides a sustainable or carbon-neutral alternative to fossil fuel feedstocks. During the conversion of biomass into useful chemicals or fuels, the recalcitrant cell wall of the biomass feedstock is first broken down into useful sugars that can be converted over chemical catalysts or enzymes. Converting sugars to biofuels or useful chemicals over biological enzymes can be costly. Therefore, current research is more aligned with the employment of functionalized metal catalysts, which are preferred owing to their stability, recyclability, and easy separability. 2-Methyltetrahydrofuran (MTHF) is a vital sugar-derived platform chemical that is used as a green solvent, fuel additive, or as the starting material for synthesizing downstream chemicals such as dienes, pentane, and 2-pentanone. Based on MTHF formation from sugar derivatives and its further conversion over catalysts, this review discusses the challenges faced during the conversion of biomass to MTHF on precious and non-precious metal-based catalysts and the successive catalytic conversion of MTHF as a platform chemical to value-added downstream chemicals. Finally, the conclusions and perspectives for this catalytic biorefinery are proposed with future recommendations.
DOI	10.1039/d2gc00759b
关键词[WOS]	VAPOR-PHASE HYDROGENATION ; REVERSIBLE DEHYDROGENATION-HYDROGENATION ; HIGHLY EFFICIENT HYDROGENATION ; AQUEOUS LEVULINIC ACID ; IN-SITU HYDROGENATION ; GAMMA-VALEROLACTONE ; SELECTIVE HYDROGENATION ; FURFURYL ALCOHOL ; ELECTROCATALYTIC HYDROGENATION ; TETRAHYDROFURFURYL ALCOHOL
收录类别	SCI
语种	英语
资助项目	National Science Foundation of China[51976220] ; National Key R&D Program of China[2019YFC1905303] ; USTC and ANSO scholarship for Young Talents
WOS研究方向	Chemistry ; Science & Technology - Other Topics
项目资助者	National Science Foundation of China ; National Key R&D Program of China ; USTC and ANSO scholarship for Young Talents
WOS类目	Chemistry, Multidisciplinary ; Green & Sustainable Science & Technology
WOS记录号	WOS:000797622900001
出版者	ROYAL SOC CHEMISTRY
引用统计	被引频次：8[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/36519
专题	中国科学院广州能源研究所
通讯作者	Liu, Qiying
作者单位	1.Univ Sci & Technol China, 96 Jinzhai Rd Baohe Dist, Hefei 230026, Anhui, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, 2 Nengyuan Rd, Guangzhou 510640, Peoples R China 3.CAS Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 4.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Alorku, Kingdom,Shen, Chen,Li, Yuhang,et al. Biomass-derived 2-methyltetrahydrofuran platform: a focus on precious and non-precious metal-based catalysts for the biorefinery[J]. GREEN CHEMISTRY,2022,24(11):4201-4236.
APA	Alorku, Kingdom,Shen, Chen,Li, Yuhang,Xu, Ying,Wang, Chenguang,&Liu, Qiying.(2022).Biomass-derived 2-methyltetrahydrofuran platform: a focus on precious and non-precious metal-based catalysts for the biorefinery.GREEN CHEMISTRY,24(11),4201-4236.
MLA	Alorku, Kingdom,et al."Biomass-derived 2-methyltetrahydrofuran platform: a focus on precious and non-precious metal-based catalysts for the biorefinery".GREEN CHEMISTRY 24.11(2022):4201-4236.