A three-dimensional ordered honeycomb nanostructure anchored with Pt-N active sites via self-assembly of a block copolymer: an efficient electrocatalyst towards the oxygen reduction reaction in fuel cells

doi:10.1039/d2ta00752e

GIEC OpenIR

	A three-dimensional ordered honeycomb nanostructure anchored with Pt-N active sites via self-assembly of a block copolymer: an efficient electrocatalyst towards the oxygen reduction reaction in fuel cells
	Wang, Zhida 1; Yang, Yi 1,2; Wang, Xiaoman 1; Lu, Zhuoxin 1; Guo, Changqing1 ; Shi, Yan 1; Tan, Hongyi 1; Shen, Lisha 1; Cao, Shuo 3; Yan, Changfeng1,2
	2022-06-07
发表期刊	JOURNAL OF MATERIALS CHEMISTRY A
ISSN	2050-7488
卷号	10 期号:22 页码:12141-12149
通讯作者	Wang, Zhida(wangzd@ms.giec.ac.cn) ; Yan, Changfeng(yancf@ms.giec.ac.cn)
摘要	Mesoporous Pt-containing nanocomposites with well-organized pores are desirable for fuel cells as well as sensors, electronics, and various chemical reactions. However, it remains challenging to construct three-dimensional (3D) ordered honeycomb-like (OHC) nanostructures with Pt species anchored in the mesopores. Herein, we show for the first time an in situ strategy of developing an N-doped ordered honeycomb (N-OHC) nanopattern with well-dispersed Pt-N-2 moieties by using the self-assembly of a block copolymer (BCP). The as-mentioned Pt including Pt single atoms (SAs) and Pt similar to 2.5 nm ultrafine nanoparticles (NPs) was hierarchically located on the inner walls and the outer surfaces of the N-OHC mesopores (Pt/N-OHC), forming well-dispersed Pt-N active sites and showing efficient catalytic activity towards the oxygen reduction reaction (ORR). By changing the film thickness of the pristine Pt/BCP template, double-layered Pt/N-OHC could be designed and the ORR activity could be correspondingly improved, for which a current density of 1.60 A cm(-2)@0.6 V and a peak power density of 1.07 W cm(-2) were observed at a very low Pt-loading of 0.04 mg cm(-2), better than 1.21 A cm(-2)@0.6 V and 0.79 W cm(-2) of the commercial Pt/C catalyst at a Pt-loading of 0.15 mg cm(-2). The electron donating behavior of Pt-N-2 and the pathway for O-2 reduction were investigated via the density functional theory (DFT) computation. The electron transfer from Pt to N gave rise to the formation of Pt-N covalent bonds, which resulted in a lower d band center and a weaker O adsorption energy and endowed the Pt/N-OHCs with enhanced ORR activity.
DOI	10.1039/d2ta00752e
关键词[WOS]	PLATINUM NANOPARTICLES ; DOPED GRAPHENE ; OXIDATION ; CO ; FE
收录类别	SCI
语种	英语
资助项目	STS Regional Key Project of the Chinese Academy of Sciences[KFJ-STS-QYZD-2021-02-003] ; Guangzhou Science and Technology Plan Project[201904010412] ; Guangzhou Science and Technology Plan Project[202002030349] ; Guangzhou Science and Technology Plan Project[202103040002]
WOS研究方向	Chemistry ; Energy & Fuels ; Materials Science
项目资助者	STS Regional Key Project of the Chinese Academy of Sciences ; Guangzhou Science and Technology Plan Project
WOS类目	Chemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary
WOS记录号	WOS:000798865000001
出版者	ROYAL SOC CHEMISTRY
引用统计	被引频次：11[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/36507
专题	中国科学院广州能源研究所
通讯作者	Wang, Zhida; Yan, Changfeng
作者单位	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China 3.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Peoples R China
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Wang, Zhida,Yang, Yi,Wang, Xiaoman,et al. A three-dimensional ordered honeycomb nanostructure anchored with Pt-N active sites via self-assembly of a block copolymer: an efficient electrocatalyst towards the oxygen reduction reaction in fuel cells[J]. JOURNAL OF MATERIALS CHEMISTRY A,2022,10(22):12141-12149.
APA	Wang, Zhida.,Yang, Yi.,Wang, Xiaoman.,Lu, Zhuoxin.,Guo, Changqing.,...&Yan, Changfeng.(2022).A three-dimensional ordered honeycomb nanostructure anchored with Pt-N active sites via self-assembly of a block copolymer: an efficient electrocatalyst towards the oxygen reduction reaction in fuel cells.JOURNAL OF MATERIALS CHEMISTRY A,10(22),12141-12149.
MLA	Wang, Zhida,et al."A three-dimensional ordered honeycomb nanostructure anchored with Pt-N active sites via self-assembly of a block copolymer: an efficient electrocatalyst towards the oxygen reduction reaction in fuel cells".JOURNAL OF MATERIALS CHEMISTRY A 10.22(2022):12141-12149.