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Microwave-assisted hydrothermal liquefaction for biomass valorization: Insights into the fuel properties of biocrude and its liquefaction mechanism
Zhuang, Xiuzheng1; Liu, Jianguo2; Wang, Chenguang1; Zhang, Qi2; Ma, Longlong2
2022-06-01
Source PublicationFUEL
ISSN0016-2361
Volume317Pages:11
Corresponding AuthorMa, Longlong(mall@seu.edu.cn)
AbstractIn contrast to the conventional liquefaction, microwave-assisted hydrothermal liquefaction (MW-HTL) is a recently developed technology for the production of biocrude for energy recovery; however, the exploration on liquefaction process under microwave radiation still presents a gap in understanding. In this study, two samples with typical components were adopted for MW-HTL, and a series of multiple techniques were used to analyze the fuel properties of biocrude as well as the corresponding changes of organic substances. Results found that microwave radiation facilitates the liquefaction process by inhibiting the secondary reactions during heating period and the excessive polymerization during liquefaction processes, resulting in an increase of approximately 39.8-43.9 % of yield, 3.9-4.0 % of higher heating values, and 46.6-59.0 % of energy recovery efficiency than that of biocrude obtained from the conventional liquefaction under similar conditions. The interaction depends on a process termed dipolar polarization was found as the main reason for this improvement, which involves the adsorption of microwave radiation by polar groups in sample within the MW field. Overall, these findings not only provide an efficient process to produce biocrude with superior quality, but also offer a fundamental support on biomass valorization in terms of energy utilization.
KeywordMicrowave heating Hydrothermal liquefaction Biomass valorization Bio-fuel properties
DOI10.1016/j.fuel.2022.123462
WOS KeywordBIO-OIL ; DEPOLYMERIZATION ; OPTIMIZATION ; CHEMICALS ; LIGNIN ; PINE ; HTL
Indexed BySCI
Language英语
Funding ProjectNational Key R&D Program of China[2018YEB1501504] ; Special Program for Key Basic Research of Guangdong Province[2020B1111570001] ; National Science Foundation for Post-doctoral Scientists of China[2020M682940]
WOS Research AreaEnergy & Fuels ; Engineering
Funding OrganizationNational Key R&D Program of China ; Special Program for Key Basic Research of Guangdong Province ; National Science Foundation for Post-doctoral Scientists of China
WOS SubjectEnergy & Fuels ; Engineering, Chemical
WOS IDWOS:000783195700007
PublisherELSEVIER SCI LTD
Citation statistics
Cited Times:15[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/36390
Collection中国科学院广州能源研究所
Corresponding AuthorMa, Longlong
Affiliation1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Peoples R China
2.Southeast Univ, Sch Energy & Environm, Minist Educ, Key Lab Energy Thermal Convers & Control, Nanjing 210096, Peoples R China
First Author AffilicationGuangZhou Institute of Energy Conversion,Chinese Academy of Sciences
Recommended Citation
GB/T 7714
Zhuang, Xiuzheng,Liu, Jianguo,Wang, Chenguang,et al. Microwave-assisted hydrothermal liquefaction for biomass valorization: Insights into the fuel properties of biocrude and its liquefaction mechanism[J]. FUEL,2022,317:11.
APA Zhuang, Xiuzheng,Liu, Jianguo,Wang, Chenguang,Zhang, Qi,&Ma, Longlong.(2022).Microwave-assisted hydrothermal liquefaction for biomass valorization: Insights into the fuel properties of biocrude and its liquefaction mechanism.FUEL,317,11.
MLA Zhuang, Xiuzheng,et al."Microwave-assisted hydrothermal liquefaction for biomass valorization: Insights into the fuel properties of biocrude and its liquefaction mechanism".FUEL 317(2022):11.
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