Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
A high energy density 3D nano-carbon based magnesium hydroxide reversible chemical reaction heat storage material synthesis and heat transfer performance investigation | |
Li, Shijie1; Yang, Xiangyu1,2; Li, Xinyu1; Qu, Wenshan1; Zhou, Tao1; Dong, Ti3; Deng, Lisheng4; Zhang, Jin1; Zhao, Jianguo1,2 | |
2022-06-01 | |
发表期刊 | JOURNAL OF ENERGY STORAGE |
卷号 | 50页码:11 |
通讯作者 | Zhang, Jin(zhangjing8014484@163.com) ; Zhao, Jianguo(zhaojianguo@sxdtdx.edu.cn) |
摘要 | Magnesium hydroxide composite chemical heat storage materials were constructed with in-situ prepared 3D-Graphene. Mg(OH)(2) particles were anchored onto the surface of the nanosupport by deposition-precipitation method. According to the heat transfer numerical simulation, addition of 3D-Graphene could greatly change the temperature distribution in the reactor and was easier to export thermal energy to the outside thermal load side. This energy storage system could output thermal energy at around 200 degrees C and absorbed heat at the range of 300-400 degrees C. Transmission electron microscopy result indicated that the particle size of Mg(OH)(2) was primarily in the range of 20-50 nm. X-ray diffraction characterization showed that the magnesium hydroxide was well dispersed in the composite material. This material provided an obviously enhanced heat storage density (610 kJ/kg), no distinct attenuation and greatly improved hydration rate compared with those of magnesium oxide because of hydrogen bonding effect in composite materials. 3D-Graphene lead to obvious decomposition activation energy decreasing of Mg(OH)(2) that would improve its utilization in the heat storage process. This was probably due to its surface effect. 3D-Graphene/Mg(OH)(2)-1 showed the lowest activation energy (116.7 kJ/mol), The thermal conductivity of the composite material was 9.4 times higher than that of Mg(OH)(2) as a result of the addition of 3D-Graphene. The proposed method provided a facile and valid technique for thermal energy utilization and the synthesis of nano-composed materials with enhanced chemical heat storage performance. |
关键词 | 3D-carbon nano-materials Heat transfer numerical simulation Thermal energy storage, magnesium hydroxide |
DOI | 10.1016/j.est.2022.104260 |
关键词[WOS] | LITHIUM HYDROXIDE ; SURFACE |
收录类别 | SCI |
语种 | 英语 |
资助项目 | Key-Area Research and Development Program of Guangdong Province[2020B0202010004] ; National Natural Science Foundation of China[52071192] |
WOS研究方向 | Energy & Fuels |
项目资助者 | Key-Area Research and Development Program of Guangdong Province ; National Natural Science Foundation of China |
WOS类目 | Energy & Fuels |
WOS记录号 | WOS:000780323200002 |
出版者 | ELSEVIER |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.giec.ac.cn/handle/344007/36313 |
专题 | 中国科学院广州能源研究所 |
通讯作者 | Zhang, Jin; Zhao, Jianguo |
作者单位 | 1.Shanxi Datong Univ, Inst Carbon Mat Sci, Datong 037009, Peoples R China 2.Taiyuan Univ Technol, Sch Mat Sci & Engn, Taiyuan 030024, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangdong Prov Key Lab New & Renewable Energy Res, 2 Nengyuan Rd, Guangzhou 510640, Peoples R China 4.Guangdong Intelligent Filling Technol Ltd Co No, 63 F3 5,Zone C,Sanshui Ind Pk, Foshan 528137, Guangdong, Peoples R China |
推荐引用方式 GB/T 7714 | Li, Shijie,Yang, Xiangyu,Li, Xinyu,et al. A high energy density 3D nano-carbon based magnesium hydroxide reversible chemical reaction heat storage material synthesis and heat transfer performance investigation[J]. JOURNAL OF ENERGY STORAGE,2022,50:11. |
APA | Li, Shijie.,Yang, Xiangyu.,Li, Xinyu.,Qu, Wenshan.,Zhou, Tao.,...&Zhao, Jianguo.(2022).A high energy density 3D nano-carbon based magnesium hydroxide reversible chemical reaction heat storage material synthesis and heat transfer performance investigation.JOURNAL OF ENERGY STORAGE,50,11. |
MLA | Li, Shijie,et al."A high energy density 3D nano-carbon based magnesium hydroxide reversible chemical reaction heat storage material synthesis and heat transfer performance investigation".JOURNAL OF ENERGY STORAGE 50(2022):11. |
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