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Corncob pyrolysis: Improvement in hydrocarbon group types distribution of bio oil from co-catalysis over HZSM-5 and activated carbon
Duan, Dengle1; Feng, Zhiqiang1; Zhang, Yongchuan1; Zhou, Tengyue1; Xu, Zhimin2; Wang, Qin1; Zhao, Yunfeng3; Wang, Chenguang4,5; Ruan, Roger6,7
2022-03-15
发表期刊WASTE MANAGEMENT
ISSN0956-053X
卷号141页码:8-15
通讯作者Xu, Zhimin(xuzhiminjnu@sina.com) ; Zhao, Yunfeng(405685129@qq.com)
摘要Zeolite and activated carbon (AC) have been demonstrated as promising and facile catalysts in degrading biomass into high-value added chemicals and bio-fuels, while the effects of combining zeolite and AC on the catalytic degradation of biomass have not been well understood. Here, co-catalytic pyrolysis of corncob over HZSM-5 and AC to produce aromatic-rich bio-oils was investigated for the first time. The effects of HZSM-5/AC ratio, pyrolysis temperature and catalyst/corncob ratio on products yields and components were explored. The optimal conversion condition was HZSM-5/AC ratio of 2:1, pyrolysis temperature of 500 celcius and catalyst/corncob ratio of 1:1. Up to 97.47% of the obtained bio-oil chemicals were jet-fuel ranged hydrocarbons, in which the selectivity of aromatics was 96.56%. The results revealed the existence of synergistic effect between HZSM-5 and AC. The present work suggested an economical and novel pathway to produce transportation jet fuel to ultimately expand the biomass application.
关键词HZSM-5 Activated carbon Corncob Aromatics Co-catalytic pyrolysis
DOI10.1016/j.wasman.2022.01.028
关键词[WOS]MICROWAVE-ASSISTED PYROLYSIS ; LOW-DENSITY POLYETHYLENE ; LIGNOCELLULOSIC BIOMASS ; IN-SITU ; CONVERSION ; AROMATICS ; CHEMICALS ; VAPORS ; LIGNIN ; WASTE
收录类别SCI
语种英语
资助项目National Natural Science of China[E129kf0401] ; CAS Key Laboratory of Renewable Energy ; College Student Innovation Fund Project of Zhongkai University of Agriculture and Engineering ; High-level Introduction of Talent Scientific Research Start-up Fund of Zhongkai University of Agriculture and Engineering
WOS研究方向Engineering ; Environmental Sciences & Ecology
项目资助者National Natural Science of China ; CAS Key Laboratory of Renewable Energy ; College Student Innovation Fund Project of Zhongkai University of Agriculture and Engineering ; High-level Introduction of Talent Scientific Research Start-up Fund of Zhongkai University of Agriculture and Engineering
WOS类目Engineering, Environmental ; Environmental Sciences
WOS记录号WOS:000784289000002
出版者PERGAMON-ELSEVIER SCIENCE LTD
引用统计
被引频次:16[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/36171
专题中国科学院广州能源研究所
通讯作者Xu, Zhimin; Zhao, Yunfeng
作者单位1.Zhongkai Univ Agr & Engn, Guangdong Prov Key Lab Lingnan Specialty Food Sci, Guangzhou 510225, Peoples R China
2.Zhongkai Univ Agr & Engn, Coll Resources & Environm, Guangzhou 510225, Peoples R China
3.Shihezi Univ, Sch Food Sci & Technol, North Fourth Rd, Shihezi 832003, Peoples R China
4.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China
5.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou 510640, Peoples R China
6.Univ Minnesota, Ctr Biorefining, 1390 Eckles Ave, St Paul, MN 55108 USA
7.Univ Minnesota, Dept Bioprod & Biosyst Engn, 1390 Eckles Ave, St Paul, MN 55108 USA
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Duan, Dengle,Feng, Zhiqiang,Zhang, Yongchuan,et al. Corncob pyrolysis: Improvement in hydrocarbon group types distribution of bio oil from co-catalysis over HZSM-5 and activated carbon[J]. WASTE MANAGEMENT,2022,141:8-15.
APA Duan, Dengle.,Feng, Zhiqiang.,Zhang, Yongchuan.,Zhou, Tengyue.,Xu, Zhimin.,...&Ruan, Roger.(2022).Corncob pyrolysis: Improvement in hydrocarbon group types distribution of bio oil from co-catalysis over HZSM-5 and activated carbon.WASTE MANAGEMENT,141,8-15.
MLA Duan, Dengle,et al."Corncob pyrolysis: Improvement in hydrocarbon group types distribution of bio oil from co-catalysis over HZSM-5 and activated carbon".WASTE MANAGEMENT 141(2022):8-15.
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